REACTIVITY AND SELECTIVITY IN THE OXIDATION OF ARYL METHYL SULFIDES AND SULFOXIDES BY HYDROGEN-PEROXIDE MEDIATED BY ACETONITRILE

被引：25

作者：

BETHELL, D ^{[1
]}

GRAHAM, AE ^{[1
]}

HEER, JP ^{[1
]}

MARKOPOULOU, O ^{[1
]}

PAGE, PCB ^{[1
]}

PARK, BK ^{[1
]}

机构：

[1] UNIV LIVERPOOL,DEPT PHARMACOL & THERAPEUT,LIVERPOOL L69 3BX,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 | 1993年 / 11期

关键词：

D O I：

10.1039/p29930002161

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In homogeneous methanol solution containing potassium carbonate, hydrogen peroxide and acetonitrile, the active oxidant in the conversion of p-substituted-phenyl methyl sulfides into the sulfoxides is selective (rho = -1.0 at 0-degrees-C) but the oxidation of the related sulfoxides at 0 and 24-degrees-C shows low selectivity, which, taken in conjunction with direct kinetic data, throws new light on the active oxidizing species in these nitrile-mediated reactions.

引用

页码：2161 / 2162

页数：2

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