MULTIDIMENSIONAL MOLECULAR-METALS WITH PI-ACCEPTOR M(DMIT)2 AND ANALOGOUS MOLECULES

被引：25

作者：

KOBAYASHI, H ^{[1
]}

KATO, R ^{[1
]}

KOBAYASHI, A ^{[1
]}

机构：

[1] UNIV TOKYO,FAC SCI,DEPT CHEM,TOKYO 113,JAPAN

来源：

SYNTHETIC METALS | 1991年 / 42卷 / 03期

关键词：

D O I：

10.1016/0379-6779(91)91411-3

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Crystal and electronic structures and resistivity of a new molecular metal C7H16N[Ni(dmit)2]2 were examined. Ni(dmit)2 molecules are arranged to form metal layers, with taking the "spanning overlapping mode". Extended Huckel band structure gave two-dimensional Fermi surface. The system is metallic at least down to 1.5 K. The synthesis of dmis (bis(2-selenone-1,3-dithiole-4,5-dithiolato)) ligand and the electrochemical data of Ni(dmis)2 are also reported.

引用

页码：2495 / 2498

页数：4

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