REACTIONS OF ISOTHIOCYANATES AND ISOCYANATES WITH SOME SILYLATED NITROGEN-CONTAINING NUCLEOPHILES

被引：5
|
作者：
GONDA, J
ANTALOVA, Z
机构：
来源：
COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS | 1991年 / 56卷 / 03期
关键词：
D O I：
10.1135/cccc19910685
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Aryl isothiocyanates and arylisocyanates react with N,O-bis(trimethylsilyl)acetamide to give N-methyl-N'-arylthioureas and ureas. Also nucleophilic additions of other aprotic nucleophiles (e.g. N-trimethylsilylimidazole, N-trimethylsilylpiperidine and N-trimethylsilylmorpholine) to the N = C = X (X = O, S) group were investigated.
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页码：685 / 694
页数：10
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