STRUCTURE OF TRANS-CARBONYLMETHYLBIS(TRI-P-TOLYLPHOSPHINE)IRIDIUM(I), TRANS-[IR(CO)(CH3)(P(P-C6H4CH3)3)2]

被引：2

作者：

JANIK, TS ^{[1
]}

CHURCHILL, MR ^{[1
]}

SEE, RF ^{[1
]}

RANDALL, SL ^{[1
]}

MCFARLAND, JM ^{[1
]}

ATWOOD, JD ^{[1
]}

机构：

[1] SUNY BUFFALO,DEPT CHEM,BUFFALO,NY 14214

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1992年 / 48卷

关键词：

D O I：

10.1107/S0108270191014890

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

[Ir(CO)(CH3){P(C7H7)3}2], C44H45IrOP2, M(r) = 843.9, orthorhombic, Pna2(1), a = 21.654 (3), b = 10.581 (1), c = 16.820 (1) angstrom, V = 3853.8 (6) angstrom3, Z = 4, D(x) = 1.455 g cm-3, lambda(Mo K-alphaBAR) = 0.71073 angstrom, mu(Mo K-alpha) = 35.62 cm-1, F(000) = 1696, T = 295 K, R = 5.73, wR = 5.01% for 3527 unique data and R = 3.08, wR = 3.82% for 2291 data with F(o) > 6.0-sigma(F(o)). The central Ir(I) atom has a square-planar coordination environment in which Ir-P(1) = 2.305 (3), Ir-P(2) 2.302 (3), Ir-CH3 = 2.206 (13) and Ir-CO = 1.867 (17) angstrom.

引用

页码：1493 / 1495

页数：3

共 50 条

[1] STRUCTURE OF TRI-P-TOLYLPHOSPHINE OXIDE HEMIHYDRATE, P(P-C6H4CH3)3O.1/2H2O
CHURCHILL, MR
SEE, RF
RANDALL, SL
ATWOOD, JD
[J]. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1993, 49 : 345 - 347
[2] PT-NOX CHEMISTRY - PREPARATION AND STRUCTURE OF TRANS-DINITROBIS(TRI-P-TOLYLPHOSPHINE)PLATINUM(II), PT(NO2)2(P(P-C6H4CH3)3)2
KADUK, JA
IBERS, JA
[J]. INORGANIC CHEMISTRY, 1977, 16 (12) : 3278 - 3282
[3] STRUCTURES OF TRANS-[TCCL4(P(CH3)3)2] AND [P(C7H7)3(C(CH3)2CH2COCH3)]2[TCCL6]
ROCHON, FD
MELANSON, R
[J]. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1993, 49 : 1259 - 1262
[4] NEUTRAL, CATIONIC, AND DICATIONIC RUTHENIUM(II) COMPLEXES OF SECONDARY CARBENES CHNH(P-C6H4CH3) AND CHN(CH3)(P-C6H4CH3)
CHRISTIA.DF
ROPER, WR
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1974, 80 (02) : C35 - C38
[5] SYNTHESIS AND CHARACTERIZATION OF NEW SQUARE-PLANAR IRIDIUM COMPLEXES [TRANS-IR(CO)L(2)X] (L=PCY(3), X=OH OR OCH3 L=P(P-TOLYL)(3), X=OCH2C6H5 OR O(P-C6H4CH3)) - CRYSTAL AND MOLECULAR-STRUCTURES OF TRANS-IR(CO)(OH)(PCY(3))(2), TRANS-IR(CO)(OCH2C(6)H(5))(P(P-TOLYL)(3))(2), AND TRANS-IR(CO)(O-P-C6H4CH3)(P(P-TOLYL)(3))(2)
MILLER, CA
JANIK, TS
LAKE, CH
TOOMEY, LM
CHURCHILL, MR
ATWOOD, JD
[J]. ORGANOMETALLICS, 1994, 13 (12) : 5080 - 5087
[6] SYNTHESIS AND PHOTOCHEMICAL STUDY OF CU(I) COMPLEXES WITH TRI-P-TOLYLPHOSPHINE AND HETEROCYCLIC THIONES - THE CRYSTAL-STRUCTURE OF [CUCL(PYMTH)(P-CH3C6H4)3P]2
KARAGIANNIDIS, P
HADJIKAKOU, SK
ASLANIDIS, P
HOUNTAS, A
[J]. INORGANICA CHIMICA ACTA, 1990, 178 (01) : 27 - 34
[7] SYNTHESIS, CHARACTERIZATION AND REACTIVITY STUDIES OF NEW VASKA-TYPE COMPLEXES, TRANS-IR(CO)(OR)L2 (L=P(P-TOLYL)3, R=CH2C6H5 OR P-C6H4CH3 - L=PCY3 (CY=CYCLOHEXYL), R=H OR CH3)
MILLER, CA
ATWOOD, JD
[J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1994, 207 : 186 - INOR
[8] CRYSTAL-STRUCTURES OF TRANS-[COCL2((CH3)2PCH2CH2P(CH3)2)2]CLO4, TRANS(CL,CL)CIS(P,P)-[COCL2(NH2CH2CH2P(CH3)2)2]PF6.0.5CH3OH, AND TRANS-[COCL2(NH2CH2CH2NH2)2]NO3
KITA, M
KASHIWABARA, K
FUJITA, J
TANAKA, H
OHBA, S
[J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1994, 67 (09) : 2457 - 2462
[9] Carbonylation reaction of alkyl complexes of iron and molecular structure of cis,trans-[Fe(CO)(2)(PME3)(2)(CH3)I] and trans,trans-[Fe(CO)(2)(PMe3)(2)(CH3)I]
Bellachioma, G
Cardaci, G
Macchioni, A
Reichenbach, G
Foresti, E
Sabatino, P
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1997, 531 (1-2) : 227 - 235
[10] SYNTHESIS AND CHARACTERIZATION OF RH(P(CH3)3)2(CO)CH3 AND RH(P(CH3)3)2(CO)PH
BOYD, SE
FIELD, LD
HAMBLEY, TW
PARTRIDGE, MG
[J]. ORGANOMETALLICS, 1993, 12 (05) : 1720 - 1724

← 1 2 3 4 5 →