CATALYTIC ASYMMETRIC C-C BOND FORMATION - NEW ENOLATOLITHIUM AND ORGANOLITHIUM CHEMISTRY

被引：26
|
作者：
BERRISFORD, DJ
机构：
[1] Department of Chemistry, University of Manchester, Institute of Science, Manchester, M60 1QD
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 02期
关键词：
ASYMMETRIC SYNTHESIS; CATALYSIS; LITHIUM COMPOUNDS;
D O I：
10.1002/anie.199501781
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Catalytic and enantioselective are two new efficient processes for CC bond formation developed from fundamental reactions of organolithium compounds. Koga et al. have achieved the benzylation of Li enolates in the presence of both chiral (L*) and achiral (L) ligands [Eq.(a)], and Denmark et al. describe the addition of RLi to aryl imines [Eq. (b)] with very good selectivities, R  Me, vinyl. (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany
引用
收藏
页码：178 / 180
页数：3
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