Structure of the product formed via Cu(I)-promoted oxidative dimerization of exo-8-ethynylpentacyclo[5.4.0.0(2,6).0(3,10).0(5,9)]undecan-endo-8-ol

被引:1
|
作者
Bott, SG
Marchand, AP
Talafuse, LK
Rajagopal, D
机构
[1] Department of Chemistry, University of North Texas, Denton, 76203, Texas
关键词
crystal structure; diyne; oxidative dimerization;
D O I
10.1007/BF01667022
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The structure consists of two acetyl-substituted PCU cages linked by a diyne fragment. The conformation about the linker is midway between staggered and eclipsed, and the acetyl groups are somewhat distorted due to the proximity to the bulky cage units.
引用
收藏
页码:543 / 547
页数:5
相关论文
共 43 条
  • [1] SYNTHESIS AND STRUCTURE OF EXO-11-CYANO-ENDO-11-(TRIMETHYLSILYLOXY)PENTACYCLO[5.4.0.0(2,6).0(3,10).0(5,9)]UNDECAN-8-ONE
    BOTT, SG
    MARCHAND, AP
    VIDYANAND, D
    SACHLEBEN, RA
    JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 1995, 25 (05) : 267 - 271
  • [2] 8-PENTACYCLO[6.3.0.0(2,6).0(3,10).0(5,9)]UNDEC-3'-YL-EXO-PENTACYCLO[5.4.0.0(2,6).0(3,10).0(5,9)]UNDECANE
    WATSON, WH
    KASHYAP, RP
    MARCHAND, AP
    DESHPANDE, MN
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1993, 49 : 1862 - 1865
  • [3] STRUCTURE OF A C26H28 ALKENE FORMED VIA TITANIUM-PROMOTED REDUCTIVE DIMERIZATION OF 4-(SPIROCYCLOPROPYL)-PENTACYCLO[5.4.0.0(2,6).0(3,10).0(5,9)]UNDECAN-8-ONE
    MARCHAND, AP
    SOROKIN, VD
    WATSON, WH
    CARLSON, TF
    KRAWIEC, M
    STRUCTURAL CHEMISTRY, 1994, 5 (06) : 367 - 373
  • [4] PENTACYCLO[5.4.0.0(2,6).0(3,10).0(5,9)]UNDECANE HYDROXYDERIVATIVES
    ALEKSANDROV, AM
    TUROV, AV
    KORNILOV, MY
    KUKHAR, VP
    ZHURNAL ORGANICHESKOI KHIMII, 1991, 27 (12): : 2566 - 2572
  • [5] PENTACYCLO[5.4.0.0/2,6/0/3,10/0/5,9]UNDECYLAMINES - SYNTHESIS AND PHARMACOLOGY
    OLIVER, DW
    DEKKER, TG
    SNYCKERS, FO
    EUROPEAN JOURNAL OF MEDICINAL CHEMISTRY, 1991, 26 (04) : 375 - 379
  • [6] SYNTHESIS OF 4,4,8,8,11,11-HEXANITROPENTACYCLO[5.4.0.0/2,6/0/3,10/0/5,9]-UNDECANE
    MARCHAND, AP
    DAVE, PR
    RAJAPAKSA, D
    ARNEY, BE
    FLIPPENANDERSON, JL
    GILARDI, R
    GEORGE, C
    JOURNAL OF ORGANIC CHEMISTRY, 1989, 54 (07): : 1769 - 1771
  • [7] STUDIES OF SCHMIDT-TYPE REARRANGEMENTS OF PENTACYCLO[5.4.0.0(2,6).0(3,10).0(5,9)]UNDECAN-8-ONE - UNEXPECTED INCURSION OF THE HUISGEN REARRANGEMENT
    MARCHAND, AP
    SOROKIN, VD
    RAJAGOPAL, D
    BOTT, SG
    HETEROCYCLES, 1995, 40 (01) : 223 - 230
  • [8] STUDIES OF SCHMIDT-TYPE REARRANGEMENTS OF PENTACYCLO[5.4.0.0(2,6).0(3,10).0(5,9)]-UNDECAN-8-ONE - UNEXPECTED INCURSION OF THE HUISGEN REARRANGEMENT
    MARCHAND, AP
    SOROKIN, VD
    RAJAGOPAL, D
    BOTT, SG
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1994, 208 : 148 - ORGN
  • [9] SYNTHESIS OF HEXACYCLO[5.4.0.0/2,6/0/3,10/0/5,9/0/8,11]UNDECANE-8-CARBOXYLIC ACID (HOMOPENTAPRISMANE-8-CARBOXYLIC ACID)
    MARCHAND, AP
    DESHPANDE, MN
    JOURNAL OF ORGANIC CHEMISTRY, 1989, 54 (13): : 3226 - 3229
  • [10] Structure and conformation of the hydrate of 8,11-dihydroxypentacyclo[5.4.0.0(2,6).0(3,10).0(5,9)]undecane-8,11-carbolactam
    Kruger, HG
    Martins, FJC
    Viljoen, AM
    Boeyens, JCA
    Cook, LM
    Levendis, DC
    ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1996, 52 : 838 - 841