SOLID SUBSTITUTIONAL SOLUTIONS ZNXMG1-XB4O7 (O LESS-THAN-OR-EQUAL-TO X LESS-THAN-OR-EQUAL-TO 1)

被引：0

作者：

LAUREIRO, Y

VEIGA, ML

ARRIBAS, C

JEREZ, A

PICO, C

机构：

来源：

EUROPEAN JOURNAL OF SOLID STATE AND INORGANIC CHEMISTRY | 1991年 / 28卷 / 3-4期

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D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Solid solutions Zn(x)Mg(1-x)B4O7 were obtained by a solid state reaction between B(OH)3, ZnO and Mg(OH)2 in appropriate molar ratios under static initial vacuum of 10(-4)- 10(-5) Hg mm in mild conditions of temperature (523-623 K). This method of synthesis has been applied successfully by us to the isolation of related metallic borates. The characterization of these materials has been carried out by X- ray powder and electron diffractions giving orthorhombic symmetry (S.G. Pbca, No. 61). The unit cell parameters change linearly with composition.

引用

页码：749 / 754

页数：6

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