RADIATION-INDUCED OXIDATIVE-DEGRADATION OF ETHYLENE PROPYLENE RUBBER BY IR SPECTROSCOPY

被引：0
|
作者：
BACCARO, S [1 ]
BUONTEMPO, U [1 ]
机构：
[1] UNIV LAQUILA,DIPARTIMENTO FIS,I-67100 LAQUILA,ITALY
来源：
RADIATION PHYSICS AND CHEMISTRY | 1992年 / 40卷 / 03期
关键词：
D O I：
暂无
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Infrared absorption spectroscopy has been used to investigate the effect of gamma-radiation on copolymer ethylene propylene (EPR). The IR spectra showed that exposure of EPR samples to gamma doses from 50 kGy to 0.6 MGy results in noticeable changes in their absorption bands, in particular an appearance of a C=O band at 1720 cm-1 and O-H band at 3450 cm-1. The dependence of the 1720 cm-1 band as a function of dose and dose rate is reported and discussed in terms of a simple model for the oxidation process.
引用
收藏
页码：175 / 180
页数：6
相关论文
共 50 条
  • [1] RADIATION-INDUCED OXIDATIVE-DEGRADATION OF ISOTACTIC POLYPROPYLENE
    HEGAZY, EA
    SEGUCHI, T
    ARAKAWA, K
    [J]. JOURNAL OF APPLIED POLYMER SCIENCE, 1981, 26 (04) : 1361 - 1372
  • [2] RADIATION-INDUCED OXIDATIVE-DEGRADATION OF POLYVINYL-CHLORIDE)
    HEGAZY, ESA
    SEGUCHI, T
    MACHI, S
    [J]. JOURNAL OF APPLIED POLYMER SCIENCE, 1981, 26 (09) : 2947 - 2957
  • [3] IMPORTANCE OF THE AMORPHOUS FRACTION OF POLYPROPYLENE IN THE RESISTANCE TO RADIATION-INDUCED OXIDATIVE-DEGRADATION
    KAGIYA, T
    NISHIMOTO, S
    WATANABE, Y
    KATO, M
    [J]. POLYMER DEGRADATION AND STABILITY, 1985, 12 (03) : 261 - 275
  • [4] Evaluation of radiation degradation of ethylene propylene rubber
    Kim, KY
    Lee, C
    Ryu, BH
    Kim, KJ
    [J]. PROCEEDINGS OF THE 7TH INTERNATIONAL CONFERENCE ON PROPERTIES AND APPLICATIONS OF DIELECTRIC MATERIALS, VOLS 1-3, 2003, : 1057 - 1060
  • [5] RADIATION-INDUCED OXIDATIVE-DEGRADATION OF POLYMERS .3. EFFECT OF RADIATION ON MECHANICAL-PROPERTIES
    SEGUCHI, T
    ARAKAWA, K
    ITO, M
    HAYAKAWA, N
    MACHI, S
    [J]. RADIATION PHYSICS AND CHEMISTRY, 1983, 21 (06): : 495 - 501
  • [6] RADIATION-INDUCED OXIDATIVE-DEGRADATION OF POLYMERS .2. EFFECTS OF RADIATION ON SWELLING AND GEL FRACTION OF POLYMERS
    SEGUCHI, T
    ARAKAWA, K
    HAYAKAWA, N
    WATANABE, Y
    KURIYAMA, I
    [J]. RADIATION PHYSICS AND CHEMISTRY, 1982, 19 (04): : 321 - 327
  • [7] RADIATION-INDUCED OXIDATIVE-DEGRADATION OF POLY[BIS(PARA-TOLYLAMINO)] PHOSPHAZENE IN CHLORINATED HYDROCARBONS
    BEGGIATO, G
    EMMI, SS
    LORA, S
    MARTELLI, A
    MINTO, F
    [J]. EUROPEAN POLYMER JOURNAL, 1984, 20 (05) : 455 - 462
  • [8] THE OXIDATIVE-DEGRADATION OF ETHYLENE VINYL ALCOHOL COPOLYMERS
    CARLSSON, DJ
    CHMELA, S
    WILES, DM
    [J]. POLYMER DEGRADATION AND STABILITY, 1991, 31 (03) : 255 - 267
  • [9] Study of radiation-induced graft copolymerization of vinyl acetate onto ethylene-co-propylene rubber
    Fang, YE
    Lu, XB
    Wang, SZ
    Zhao, X
    Fang, F
    [J]. JOURNAL OF APPLIED POLYMER SCIENCE, 1996, 62 (13) : 2209 - 2213
  • [10] Radiation-induced effects in ethylene-propylene copolymer with antioxidant
    Baccaro, S
    [J]. IRRADIATION OF POLYMERS: FUNDAMENTALS AND TECHNOLOGICAL APPLICATIONS, 1996, 620 : 323 - 339
12345