LIQUID-LIQUID-EXTRACTION AND SPECTROPHOTOMETRIC DETERMINATION OF PALLADIUM(II) WITH ISONITROSOMALONDIANILIDE

被引:0
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作者
CHAUDHARI, RA [1 ]
SAWANT, AD [1 ]
机构
[1] INST SCI, DEPT CHEM, DIV INORGAN & NUCL CHEM, 15 MADAM CAMA RD, BOMBAY 400032, INDIA
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中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Isonitrosomalondianilide (HIMDA) is proposed as a new reagent for the selective extraction and photometric determination of Pd(II). The reagent forms a yellow water-insoluble complex with palladium in the pH range 2-4.25. The complex is extracted with chloroform and its absorbance measured against a reagent blank spectrophotometrically at 385 nm. The effects of experimental variables and diverse ions are reported. The proposed method is highly selective and rapid for the estimation of palladium at trace levels.
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页码:643 / 645
页数:3
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