CHEMOSORPTION AND OXIDATION OF CARBON-MONOXIDE ON PALLADIUM ALLOYS

被引：0

作者：

YATSIMIRSKY, VK ^{[1
]}

机构：

[1] TG SHEVCHENKO STATE UNIV,KIEV,UKRAINE,USSR

来源：

TEORETICHESKAYA I EKSPERIMENTALNAYA KHIMIYA | 1991年 / 27卷 / 05期

关键词：

D O I：

暂无

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Kinetic and adsorptional (programmed thermodesorption in situ) data obtained from the oxidation reaction of carbon monoxide on palladium alloys with silver and gold are discussed. It is shown that the local interaction is decisive and active cluster-sites being palladium-monoatomic and binding weakly a chemosorbed CO molecule are optimal for the catalysis. Silver activates the second component: oxygen. The cluster model permits predicting optimal composition of Pd-Ag-catalysts of CO oxidation and explaining the activity/composition dependence for Pd-Au samples.

引用

页码：574 / 578

页数：5

共 50 条

[1] OXIDATION OF CARBON-MONOXIDE ON PALLADIUM
PARK, RL
SCHREINE.DG
[J]. JOURNAL OF VACUUM SCIENCE & TECHNOLOGY, 1974, 11 (01): : 248 - 248
[2] OXIDATION OF CARBON-MONOXIDE CATALYZED BY PALLADIUM
CLOSE, JS
WHITE, JM
[J]. JOURNAL OF CATALYSIS, 1975, 36 (02) : 185 - 198
[3] INVESTIGATIONS ON THE ADSORPTION AND ELECTROCATALYTIC OXIDATION OF CARBON-MONOXIDE ON GOLD + PALLADIUM ALLOYS
GOSSNER, K
MIZERA, E
[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1982, 140 (01) : 35 - 45
[4] THE OXIDATION OF CARBON-MONOXIDE ON UNSUPPORTED AND SUPPORTED PALLADIUM
VORONTSOV, AV
KASATKINA, LA
[J]. KINETICS AND CATALYSIS, 1980, 21 (05) : 932 - 938
[5] CATALYTIC-OXIDATION OF CARBON-MONOXIDE ON THE SURFACES OF SILVER - PALLADIUM - YTRIUM ALLOYS
LAZAROV, D
MANEV, S
MANEV, V
STANTCHEVA, M
[J]. MATERIALS CHEMISTRY, 1979, 4 (01): : 81 - 91
[6] EFFECT OF PREPARATION CONDITIONS ON THE CATALYTIC ACTIVITY OF PALLADIUM SILVER ALLOYS IN THE OXIDATION OF CARBON-MONOXIDE
YATSIMIRSKII, VK
BOLDYREVA, NA
MARCHUK, TV
[J]. KINETICS AND CATALYSIS, 1983, 24 (01) : 115 - 119
[7] OXIDATION OF CARBON-MONOXIDE BY OXYGEN ON PALLADIUM AND RUTHENIUM CATALYST
PALKA, J
GREGOR, M
[J]. CHEMICKE ZVESTI, 1972, 26 (02): : 140 - &
[8] OXIDATION OF CARBON-MONOXIDE ON PALLADIUM - ROLE OF THE ALUMINA SUPPORT
RUMPF, F
POPPA, H
BOUDART, M
[J]. LANGMUIR, 1988, 4 (03) : 722 - 728
[9] PECULIARITIES OF CATALYTIC-OXIDATION OF CARBON-MONOXIDE ON PALLADIUM
OSTAPYUK, VA
BOLDYREVA, NA
KORNEICHUK, GP
[J]. DOPOVIDI AKADEMII NAUK UKRAINSKOI RSR SERIYA B-GEOLOGICHNI KHIMICHNI TA BIOLOGICHNI NAUKI, 1980, (11): : 56 - 58
[10] OXIDATION OF CARBON-MONOXIDE OVER A PALLADIUM CHLORIDE ACTIVE CARBON CATALYST
FUJIMOTO, K
IUCHI, K
KUNUGI, T
[J]. INTERNATIONAL CHEMICAL ENGINEERING, 1972, 12 (04): : 741 - &

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