SYNTHESIS OF PENTAFLUOROETHYL TRIFLUOROACETATE BY LOW-TEMPERATURE DIRECT FLUORINATION

被引：1

作者：

ARIMURA, T

SHIBAKAMI, M

TAMURA, M

KUROSAWA, S

SEKIYA, A

机构：

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1993年 / 66卷 / 08期

关键词：

D O I：

10.1246/bcsj.66.2454

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Ethyl acetate was perfluorinated by direct fluorination in the presence of cesium fluoride, affording pentafluoroethyl trifluoroacetate in excellent yield. In the reaction pathway, the dimerization of trifluoroacetyl fluoride with cesium fluoride gives pentafluoroethyl trifluoroacetate.

引用

页码：2454 / 2456

页数：3

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