THE ROLE OF SYMMETRY IN COLLISIONS OF N2 WITH N2+

被引：13

作者：

SOHLBERG, K ^{[1
]}

FUTRELL, J ^{[1
]}

SZALEWICZ, K ^{[1
]}

机构：

[1] UNIV DELAWARE, DEPT CHEM & BIOCHEM, NEWARK, DE 19716 USA

来源：

JOURNAL OF CHEMICAL PHYSICS | 1991年 / 94卷 / 10期

关键词：

D O I：

10.1063/1.460278

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Classical trajectory methods have been used to explore the excitation of vibrations in gas-phase collisions of the nitrogen molecular ion with its parent molecule. The near symmetry of the reactants is shown to result in a high probability that the two molecules are excited by an equal amount of energy. This provides a possible explanation of the molecular beam measurements that show that the total number of vibrational energy quanta excited in the collision is, with a high probability, even.

引用

页码：6500 / 6507

页数：8

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