SELECTIVE HYDROGENATION OF O-XYLENE ON NOBLE-METALS - THERMAL EFFECT IN SELECTIVITY

被引：7
|
作者：
DELANGEL, G
BERTIN, V
PEREZ, A
GOMEZ, R
机构：
[1] Department of Chemistry, Universidad Autonoma Metropolitana-Iztapalapa, 09340, D. F.
来源：
REACTION KINETICS AND CATALYSIS LETTERS | 1992年 / 48卷 / 01期
关键词：
D O I：
10.1007/BF02070094
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Selective hydrogenation of o-xylene on silica supported noble metals Pd, Rh, Ni, Pt, Ir, Ru, Os and Re has been studied. A correlation between the heat capacity of the metal conduction electrons and the selectivity towards the cis-product was found. Thermal effect in activity and selectivity is reported.
引用
收藏
页码：259 / 264
页数：6
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