ASYMMETRIC HYDROGENATION IN WATER BY A RHODIUM COMPLEX OF SULFONATED 2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL (BINAP)

被引：56
|
作者：
WAN, KT [1 ]
DAVIS, ME [1 ]
机构：
[1] CALTECH,DIV CHEM & CHEM ENGN,PASADENA,CA 91125
来源：
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 16期
关键词：
D O I：
10.1039/c39930001262
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The synthesis of sulfonated 2,2'-bis(diphenylphosphino)-1,1'-binaphthyl (binap) is reported; a rhodium complex of this ligand is the first to perform asymmetric hydrogenation in neat water with optical yields as high as those obtained in nonaqueous solvent.
引用
收藏
页码：1262 / 1264
页数：3
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