FORMYLATION OF AROMATIC-COMPOUNDS UNDER ATMOSPHERIC CO PRESSURE

被引:0
|
作者
SOUMA, Y
TANAKA, M
机构
来源
ACID-BASE CATALYSIS II | 1994年 / 90卷
关键词
D O I
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中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Formylation of aromatic compounds such as toluene, xylene, mesitylene, and halogenatedbenzene was carried out in HSO3F-SbF5 under atmospheric CO pressure at 0 degrees C. In HSO3F-SbF5, both formylation and sulfonylation took place to give formyl and sulfonyl compounds depending on the acidity of the solution. Diformylation of polynuclear aromatic compounds such as naphthalene, diphenyl, diphenylmethane and dibenzyl was carried out in HF-SbF5 system by a one-pot reaction.
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页码:93 / 96
页数:4
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