SYNTHESIS, CHARACTERIZATION AND THE CRYSTAL-STRUCTURE OF A CIS-DIOXOVANADIUM(V) COMPLEX OF A TRIDENTATE SCHIFF-BASE LIGAND

被引：9

作者：

LIU, HX ^{[1
]}

WANG, W ^{[1
]}

WANG, X ^{[1
]}

TAN, MY ^{[1
]}

机构：

[1] LANZHOU UNIV,CTR INSTRUMENTAL ANAL & RES,LANZHOU 730000,PEOPLES R CHINA

来源：

JOURNAL OF COORDINATION CHEMISTRY | 1994年 / 33卷 / 04期

关键词：

CIS-DIOXOVANADIUM; SCHIFF BASE; TERDENTATE; CRYSTAL STRUCTURE;

D O I：

10.1080/00958979408024294

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The title complex, [VO2{C6H5C(O)CHC(CH3)NNC(O)CH2(NC5H5)}].C2H5OH, was synthesized and characterized by elemental analysis and spectroscopy. Yellow crystals of the complex are monoclinic, space group P2(1)/a with a = 10.690(2), b = 16.008(3), c = 13.164(4)Angstrom, beta = 107.03(2)degrees, V = 2153.9(18)Angstrom(3), F(000) = 880 and Dc = 1.305 g cm(-3) for Z = 4. X-ray structure analysis shows that the vanadium coordination number is five and the coordination polyhedron is a distorted trigonal bipyramid.

引用

页码：347 / 352

页数：6

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