NONCHELATION CONTROLLED 1,3-ASYMMETRIC INDUCTION IN BETA-CHIRAL ACYLSILANES

被引：38
|
作者：
NAKADA, M [1 ]
URANO, Y [1 ]
KOBAYASHI, S [1 ]
OHNO, M [1 ]
机构：
[1] UNIV TOKYO,FAC PHARMACEUT SCI,BUNKYO KU,TOKYO 113,JAPAN
来源：
TETRAHEDRON LETTERS | 1994年 / 35卷 / 05期
关键词：
D O I：
10.1016/S0040-4039(00)75805-9
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The diastereoselectivity of nucleophilic adition to beta-chiral acylsilanes is examined, and our method is applied to the stereoselective synthesis of calcitriol lactone, a major metabolite of vitamine D-3.
引用
收藏
页码：741 / 744
页数：4
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