REDOX-ACTIVE ORGANOMETALLIC IR COMPLEXES CONTAINING BIPHENYL-2,2'-DIYL

被引：44
|
作者：
LU, Z
JUN, CH
DEGALA, SR
SIGALAS, M
EISENSTEIN, O
CRABTREE, RH
机构：
[1] UNIV PARIS 11,CHIM THEOR LAB,F-91405 ORSAY,FRANCE
[2] YALE UNIV,DEPT CHEM,NEW HAVEN,CT 06511
来源：
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 24期
关键词：
D O I：
10.1039/c39930001877
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The redox-active complexes [Ir(PPh3)2(biph)Cl] 3 and [Ir(PMe3)3(biph)Cl] 6 contain biphenyl-2,2-diyl (biph), the organometallic analogue of bipy; 3 shows an unexpected five-coordinate structure lying between T and Y geometry and oxidation of 6 by NOBF4 gives [Ir(PMe3)3(biphBF)Cl]+ (8)+, an unprecedented Ir(IV) boryl complex.
引用
收藏
页码：1877 / 1880
页数：4
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