PREPARATION, CRYSTAL-STRUCTURES, CONDUCTIVITIES AND ELECTRONIC-STRUCTURES OF [ET]3[NICL4]CENTER-DOT-H2O AND [ET]3[AUBR4] [ET = BIS(ETHYLENEDITHIO)TETRATHIAFULVALENE]

被引：12

作者：

MARTIN, JD

CANADELL, E

FITZMAURICE, JC

SLAWIN, AMZ

WILLIAMS, DJ

WOOLLINS, JD

机构：

[1] UNIV LONDON IMPERIAL COLL SCI TECHNOL & MED,DEPT CHEM,LONDON SW7 2AY,ENGLAND

[2] UNIV PARIS 11,CNRS,URA 506,CHIM THEOR LAB,F-91405 ORSAY,FRANCE

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1994年 / 13期

关键词：

D O I：

10.1039/dt9940001995

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Single-crystal studies of [et]3[NiCl4].H2O and [et]3[AuBr4] [et = bis(ethylenedithio)tetrathiafulvalene] have revealed distinctly different packing motifs associated with the different anions. The nickel compound contains a sheet stack structure whilst the gold compound has a herringbone stack of et molecules. The stacking properties are discussed in the context of conductivity and band-theory calculations. The nickel compound exhibits metallic behaviour at room temperature.

引用

页码：1995 / 2004

页数：10

共 50 条

[1] [ET]3[NICL4].H2O - A METALLIC CONDUCTOR CONTAINING THE NICL42- ANION IN A DISTORTED SQUARE-PLANAR GEOMETRY [ET = BIS(ETHYLENEDITHIO)TETRATHIAFULVALENE]
FITZMAURICE, JC
SLAWIN, AMZ
WILLIAMS, DJ
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[2] CRYSTAL-STRUCTURES AND ELECTRICAL-PROPERTIES OF ET3CL2.2H2O AND ET4CL2.4H2O ORGANIC METALS
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[3] Structural, electrical, and magnetic properties of α-(ET)7[MnCl4]2•(1,1,2-C2H3Cl3)2 (ET = bis(ethylenedithio)tetrathiafulvalene)
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[4] Crystal structures and electrical properties of ET3Cl2&middot2H2O and ET4Cl2&middot4H2O organic metals
Shibaeva, R.P.
Lobkovskaya, R.M.
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Buravov, L.I.
Ignatiev, A.A.
Kushch, N.D.
Laukhina, E.E.
Makova, M.K.
Yagubskii, E.B.
Zvarykina, A.V.
Synthetic Metals, 1988, 27 (1-2) : 189 - 194
[5] The first radical salt of the polyoxometalate cluster [P2W18O62](6 theta) with bis(ethylenedithio)tetrathiafulvalene (ET): ET(11)[P2W18O62]center dot 3H(2)O
Coronado, E
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GimenezSaiz, C
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[6] CRYSTAL-STRUCTURE OF ETHER SOLVATE OF OCTANUCLEAR LUTETIUM ALUMINOHYDRIDE COMPLEX ([(BU(+)2C5H3)LUH]4[ET2O-CENTER-DOT-ALH4]2)CENTER-DOT-ET2O
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[7] Zirconium Reagents for Organometallic Synthesis. Crystal Structures of ZrCl4·2Et2O and (Et2N)ZrCl3·Et2O
A. N. Nesmeyanov Inst. O., Russian Academy of Sciences, 28 Vavilov st., Rus-117813 Moscow, Russia
Z. Naturforsch. Sect. B J. Chem. Sci., 12 (1563-1567):
[8] Zirconium reagents for organometallic synthesis.: Crystal structures of ZrCl4•2Et2O and (Et2N)ZrCl3•Et2O
Avtomonov, EV
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ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1999, 54 (12): : 1563 - 1567
[9] NA-2[BI2CU3O4(ASO4)(2)]CENTER-DOT-H2O AND K-2[BI2CU3O4(ASO4)(2)]CENTER-DOT(2) H2O - 2 RELATED CRYSTAL-STRUCTURES WITH TOPOLOGICALLY IDENTICAL LAYERS
EFFENBERGER, H
MILETICH, R
ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 1995, 210 (06): : 421 - 426
[10] ISOLATION AND CRYSTAL-STRUCTURES OF THE HALIDE-FREE AND HALIDE-RICH PHENYLLITHIUM ETHERATE COMPLEXES [(PHLI.ET2O)4] AND [(PHLI.ET2O)3.LIBR]
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