TRIAZINE ADDUCTS OF DIMETHYLZINC AND DIMETHYLCADMIUM - X-RAY CRYSTAL-STRUCTURE OF ME2ZN[(CH2NME)3]2

被引：43

作者：

HURSTHOUSE, MB ^{[1
]}

MOTEVALLI, M ^{[1
]}

OBRIEN, P ^{[1
]}

WALSH, JR ^{[1
]}

JONES, AC ^{[1
]}

机构：

[1] EPICHEM LTD,WIRRAL L62 3QF,MERSEYSIDE,ENGLAND

来源：

ORGANOMETALLICS | 1991年 / 10卷 / 09期

关键词：

D O I：

10.1021/om00055a041

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of various triazines of the type (CH2NR)3 with dimethylzinc and dimethylcadmium yielded a series of adducts of the type Me2M[(CH2NR)3]2 (where M = zinc or cadmium and R = methyl, ethyl, or isopropyl), of which the methyl derivative of dimethylzinc has proved useful in the growth of high-quality ZnSe by metalloorganic vapor deposition (MOCVD). The X-ray crystal structure of Me2Zn[(CH2NMe)3]2 has been determined and shows the complex to consist of monomeric units of C2-upsilon symmetry. The compound crystallizes in space group Cmcm, a = 13.553 (2) angstrom, b = 7.399 (2) angstrom, and c = 19.738 (4) angstrom, alpha = beta = gamma = 90-degrees.

引用

页码：3196 / 3200

页数：5

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