SUPPORTED AQUEOUS-PHASE ENZYMATIC CATALYSIS IN ORGANIC MEDIA

被引：11
|
作者：
PARIDA, S
DATTA, R
DORDICK, JS
机构：
[1] UNIV IOWA,DEPT CHEM & BIOCHEM ENGN,IOWA CITY,IA 52242
[2] UNIV IOWA,CTR BIOCATALYSIS & BIOPROC,IOWA CITY,IA 52242
来源：
APPLIED BIOCHEMISTRY AND BIOTECHNOLOGY | 1992年 / 33卷 / 01期
关键词：
SUPPORTED LIQUID-PHASE CATALYSIS; ALCOHOL DEHYDROGENASE; ORGANIC MEDIA;
D O I：
10.1007/BF02922179
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
The use of partially hydrated porous silica particles has been studied as a support for cofactor-dependent enzymatic catalysis in organic solvents. At an optimal pore hydration corresponding to 70% pore volume, horse liver alcohol dehydrogenase catalyzes the oxidation and reduction of alcohols and aldehydes, respectively, with rates sixfold higher than with nonporous glass beads as the enzymatic support and with cofactor recycling numbers in excess of 10(5). Thus, supported aqueous-phase enzymatic catalysis makes highly effective use of the enzyme and cofactor by coimmobilization and by providing a high interfacial area for reactions in organic media.
引用
收藏
页码：1 / 14
页数：14
相关论文
共 50 条
  • [1] SUPPORTED AQUEOUS-PHASE CATALYSIS
    DAVIS, ME
    [J]. CHEMTECH, 1992, 22 (08) : 498 - 502
  • [2] Hydrocarboxylation of olefins by supported aqueous-phase catalysis
    He, Zhenhong
    Hou, Zhenshan
    Zhang, Yagang
    Wang, Tianfu
    Dilixiati, Yierxiati
    Eli, Wumanjiang
    [J]. CATALYSIS TODAY, 2015, 247 : 147 - 154
  • [3] ASYMMETRIC-SYNTHESIS OF NAPROXEN BY SUPPORTED AQUEOUS-PHASE CATALYSIS
    WAN, KT
    DAVIS, ME
    [J]. JOURNAL OF CATALYSIS, 1994, 148 (01) : 1 - 8
  • [4] HYDROFORMYLATION BY SUPPORTED AQUEOUS-PHASE CATALYSIS - A NEW CLASS OF HETEROGENEOUS CATALYSTS
    ARHANCET, JP
    DAVIS, ME
    MEROLA, JS
    HANSON, BE
    [J]. NATURE, 1989, 339 (6224) : 454 - 455
  • [5] SUPPORTED AQUEOUS-PHASE CATALYSTS
    ARHANCET, JP
    DAVIS, ME
    MEROLA, JS
    HANSON, BE
    [J]. JOURNAL OF CATALYSIS, 1990, 121 (02) : 327 - 339
  • [6] Hydration Mediation in Supported Aqueous-Phase Catalysis for Atom Transfer Radical Polymerization
    Aggarwal, Ravi
    Baskaran, Durairaj
    [J]. MACROMOLECULES, 2011, 44 (22) : 8805 - 8818
  • [7] ENZYMATIC CATALYSIS IN ORGANIC MEDIA
    MONOT, F
    [J]. REVUE DE L INSTITUT FRANCAIS DU PETROLE, 1994, 49 (02): : 187 - 208
  • [8] SUPPORTED AQUEOUS PHASE CATALYSIS
    DAVIS, ME
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1992, 203 : 108 - IEC
  • [9] Alternative supported aqueous-phase catalyst systems
    Toth, I
    Guo, I
    Hanson, BE
    [J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1997, 116 (1-2) : 217 - 229
  • [10] NMR and enzymatic catalysis in organic media
    Decagny, B
    Roblot, C
    Sarazin, C
    Franqueville, E
    Ergan, F
    Barbotin, JN
    Seguin, JP
    [J]. JOURNAL DE CHIMIE PHYSIQUE ET DE PHYSICO-CHIMIE BIOLOGIQUE, 1998, 95 (02) : 418 - 422
12345