SYNTHESIS OF NEW FLUORINATED NONIONIC SURFACTANTS DERIVED FROM LACTOSE - THE N-[2-(F-ALKYL)ETHYL]-LACTOSYLAMINES AND N-[2-(F-ALKYL)ETHYL]-LACTOBIONAMIDES

被引:22
|
作者
ELGHOUL, M [1 ]
ESCOULA, B [1 ]
RICO, I [1 ]
LATTES, A [1 ]
机构
[1] UNIV TOULOUSE 3,INTERACT MOLEC & REACTIV CHIM & PHOTOCHIM LAB,CNRS,UA 470,F-31062 TOULOUSE,FRANCE
关键词
D O I
10.1016/S0022-1139(00)80208-0
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The synthesis of new fluorinated non-ionic surfactants derived from alpha-lactose, the N-[2-(F-alkyl)ethyl]-lactosylamines (3) and -lactobionamides (4), is described. These derivatives are readily prepared in good yield in an aza-Wittig reaction from: (i) 2-(F-alkyl)ethyl azides which are readily obtained from the corresponding 2-(F-alkyl)ethyl iodides; and (ii) a lactose (for compounds 3) and lactobionic acid (for compounds 4) without prior protection of the sugar hydroxy groups.
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页码:107 / 112
页数:6
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