SOME MECHANISTIC ASPECTS OF CARBOHYDRATE ELECTROCHEMISTRY

被引：5
|
作者：
HAMANN, CH
FISCHER, S
POLLIGKEIT, H
SCHLEIF, D
WOLF, P
机构：
[1] Fachbereich Chemie, Angewandte Physikalische Chemie, D-26111 Oldenburg/Oldb., Carl-von-Ossietzky-Universität
来源：
ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-INTERNATIONAL JOURNAL OF RESEARCH IN PHYSICAL CHEMISTRY & CHEMICAL PHYSICS | 1994年 / 185卷
关键词：
CARBOHYDRATE ELECTROCHEMISTRY; SUGAR ANIONS; ETHERIFICATION; APROTIC MEDIA;
D O I：
10.1524/zpch.1994.185.Part_1.069
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The electroreductive conversion of carbohydrates leads to anions the reactions of which with alkylating or acylating reagents results in the formation of ether or ester derivatives. The obtained substitution patterns are influenced by the acidity of the different OH-groups, by sterical effects of the trapping agents, and by the adsorption configuration of the sugar molecule on the electrode surface. With examples we show under what conditions a certain influence is dominant.
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页码：69 / 78
页数：10
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