THE TEMPERATURE-DEPENDENCE OF THE MUTUAL SOLUBILITY OF ALCOHOL HYDROCARBON MIXTURES

被引:3
|
作者
NAGATA, I
MIYAMOTO, K
机构
[1] Department of Chemistry and Chemical Engineering, Division of Physical Sciences, Kanazawa University, Kanazawa, 920
关键词
D O I
10.1016/0040-6031(92)80299-C
中图分类号
O414.1 [热力学];
学科分类号
摘要
Binary liquid-liquid equilibrium data for alcohol + saturated hydrocarbon mixtures over a wide temperature range have been well correlated with the UNIQUAC associated-solution model, whose energy parameters are assumed to be temperature dependent. The derived parameters lead to good prediction of the activity coefficients in miscible regions for the binary mixtures, and of liquid-liquid equilibria for ternary mixtures of methanol with two saturated hydrocarbons.
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页码:293 / 305
页数:13
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