ACYCLIC STEREOCONTROL VIA ORGANOGEMBISMETALLIC REAGENTS .3.

被引：0
|
作者：
MAREK, I
LEFRANCOIS, JM
NORMANT, JF
机构：
来源：
SYNLETT | 1992年 / 08期
关键词：
D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The metalla-Claisen reaction leads under very mild conditions, high chemical yields and diastereoselectivity to compounds with two adjacent asymmetric centers. For example, (Z)-1-heptenyllithium (2) was converted into (3S,4R)-3,4-dimethyl-1-nonene (5) by reaction with crotylmagnesium bromide and zinc(II) bromide and subsequent hydrolysis of the gem-1,1-bismetallic intermediate 4.
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页码：633 / 635
页数：3
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