KINETICS OF THE DEHYDROGENATION OF N-BUTANE AND ITS MIXTURES WITH PROPANE OVER PLATINUM CATALYSTS

被引：0
|
作者：
LOC, LC
GAIDAI, NA
KIPERMAN, SL
THOANG, HS
机构：
来源：
KINETICS AND CATALYSIS | 1993年 / 34卷 / 03期
关键词：
D O I：
暂无
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The kinetics of the dehydrogenation of n-butane and its mixtures with propane over potassium-platinum catalysts and those modified by indium was investigated. The addition of indium resulted in an increase in the rate and selectivity of dehydrogenation. The stepwise scheme was suggested to take into account the parallel and consecutive formation of butadiene on two types of centers. A simple, mutual influence of components was found to occur in the case of dehydrogenation of propane-butane mixtures. The dehydrogenation rates of i- and n-butanes were compared.
引用
收藏
页码：451 / 455
页数：5
相关论文
共 50 条
  • [1] KINETICS OF DEHYDROGENATION OF N-BUTANE ON PLATINUM CATALYSTS
    LOK, LK
    GAIDAI, NA
    KIPERMAN, SL
    KOGAN, SB
    [J]. KINETICS AND CATALYSIS, 1990, 31 (02) : 421 - 424
  • [2] Kinetics of propane and n-butane dehydrogenation over platinum-alumina catalysts in the presence of hydrogen and water vapor
    Loc, LC
    Gaidai, NA
    Kiperman, SL
    Thoang, HS
    [J]. KINETICS AND CATALYSIS, 1996, 37 (06) : 790 - 796
  • [3] KINETICS OF SIDE REACTIONS IN THE DEHYDROGENATION OF N-BUTANE AND ISOBUTANE OVER PLATINUM-POTASSIUM CATALYSTS
    LOC, LC
    GAIDAI, NA
    KIPERMAN, SL
    THOANG, HS
    NOVIKOV, PB
    [J]. KINETICS AND CATALYSIS, 1995, 36 (04) : 504 - 510
  • [4] Oxidative dehydrogenation of propane and n-butane over alumina supported vanadium catalysts
    Murgia, V
    Sham, E
    Gottifredi, JC
    Torres, EMF
    [J]. LATIN AMERICAN APPLIED RESEARCH, 2004, 34 (02) : 75 - 82
  • [5] Hydrogenolysis of propane and n-butane over rhodium catalysts
    Bond, GC
    Calhoun, J
    Hooper, AD
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1996, 92 (24): : 5117 - 5128
  • [6] Direct Dehydrogenation of n-Butane Over Platinum-Tin Catalysts Supported on Alumina
    Lee, Jong Kwon
    Kim, Jeong Kwon
    Kang, Ki Hyuk
    Song, In Kyu
    [J]. JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, 2016, 16 (10) : 10816 - 10822
  • [7] Dehydrogenation of n-butane over vanadia catalysts supported on θ-alumina
    Jackson, S. David
    Rugmini, Sreekala
    [J]. JOURNAL OF CATALYSIS, 2007, 251 (01) : 59 - 68
  • [8] KINETICS AND REACTION MECHANISM OF N-BUTANE WITH IODINE IN DEHYDROGENATION OF N-BUTANE
    CHEKHOV, YY
    TSAILING.AL
    IOFFE, II
    [J]. PETROLEUM CHEMISTRY, 1967, 7 (03) : 205 - &
  • [9] OXIDATIVE DEHYDROGENATION OF PROPANE AND N-BUTANE ON V-MG BASED CATALYSTS
    CORMA, A
    NIETO, JML
    PAREDES, N
    DEJOZ, A
    VAZQUEZ, I
    [J]. NEW DEVELOPMENTS IN SELECTIVE OXIDATION II, 1994, 82 : 113 - 123
  • [10] Helmholtz-Type Equations of State for Hydrocarbon Refrigerant Mixtures of Propane/n-Butane, Propane/Isobutane, n-Butane/Isobutane, and Propane/n-Butane/Isobutane
    H. Miyamoto
    K. Watanabe
    [J]. International Journal of Thermophysics, 2003, 24 : 1007 - 1031
12345