STRUCTURE OF A CHARGE-TRANSFER COMPLEX OF 3,8-DIETHYL-5,10-DIMETHYL-1,6-DIOXAPYRENE (DEDMDOP) WITH 7,7,8,8-TETRACYANO-P-QUINODIMETHANE (TCNQ)

被引：6

作者：

THORUP, N ^{[1
]}

HJORTH, M ^{[1
]}

CHRISTENSEN, JB ^{[1
]}

BECHGAARD, K ^{[1
]}

机构：

[1] UNIV COPENHAGEN,CTR INTERDISCIPLINARY STUDIES MOLEC INTERACT,DK-2100 COPENHAGEN,DENMARK

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1992年 / 48卷

关键词：

D O I：

10.1107/S0108270191010284

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

C20H20O2.C12H4N4, M(r) = 496.57, orthorhombic, Pmnn, a = 6.749 (1), b = 9.699 (2), c = 19.204 (1) angstrom, V = 1257.1 (3) angstrom 3, Z = 2, D(x) = 1.312, D(m) = 1.291 g cm-3, lambda(Mo K-alpha) = 0.71073 angstrom, mu = 0.781 cm-1, F(000) = 520, T = 294 K, R = 0.062 for 765 observed reflections. The structure is composed of stacks along the a axis of alternating DEDMDOP and TCNQ molecules positioned in mirror planes and regularly spaced by 1/2a = 3.37 angstrom. This mixed-stacking arrangement is consistent with the observed low electrical conductivity (sigma = 3 x 10(-6) S m-1).

引用

页码：530 / 533

页数：4

共 48 条

[1] THE CRYSTAL-STRUCTURE OF 1,6-DITHIAPYRENE(DTP)-7,7,8,8-TETRACYANO-P-QUINODIMETHANE(TCNQ)
THORUP, N
RINDORF, G
JACOBSEN, CS
BECHGAARD, K
JOHANNSEN, I
MORTENSEN, K
MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1985, 120 (1-4): : 349 - 352
[2] DETERMINATION OF CHARGE-TRANSFER IN MOLYBDENUM COMPLEXES OF 7,7,8,8-TETRACYANO-P-QUINODIMETHANE WITH VIBRATIONAL SPECTROSCOPY
FAULQUES, E
LEBLANC, A
MOLINIE, P
DECOSTER, M
CONAN, F
GUERCHAIS, JE
SALAPALA, J
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 1995, 51 (05): : 805 - 819
[3] Photoinduced electron transfer ring opening of α-epoxyketones using 7,7,8,8-tetracyano-p-quinodimethane (TCNQ)
H. R. Memarian
F. Nikpour
H. Sabzyan
Journal of the Iranian Chemical Society, 2007, 4 : 37 - 45
[4] Photoinduced electron transfer ring opening of α-epoxyketones using 7,7,8,8-tetracyano-p-quinodimethane (TCNQ)
Memarian, H. R.
Nikpour, F.
Sabzyan, H.
JOURNAL OF THE IRANIAN CHEMICAL SOCIETY, 2007, 4 (01) : 37 - 45
[5] CRYSTAL-STRUCTURE OF THE 2-1 CHARGE-TRANSFER SALT DERIVED FROM HEXAMETHYLENETETRASELENAFULVALENE (HMTSF) AND "7,7,8,8-TETRACYANO-P-QUINODIMETHANE (TCNQ), (HMTSF)2(TCNQ)
EMGE, TJ
BRYDEN, WA
COWAN, DO
KISTENMACHER, TJ
MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1982, 90 (1-2): : 173 - 184
[6] STRUCTURE OF THE BIS(7,7,8,8-TETRACYANO-P-QUINODIMETHANE)-4-(BENZYLMETHYLAMINOMETHYL)-2,2',5,5'-TETRATHIAFULVALENE CHARGE-TRANSFER COMPLEX
TRIKI, S
OUAHAB, L
GRANDJEAN, D
GARIN, J
URIEL, S
FABRE, JM
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1993, 49 : 1184 - 1187
[7] Crystal structure of an ionic charge-transfer complex of DAP-F4TCNQ (DAP=1,6-diaminopyrene, F4TCNQ=2,3,5,6-tetrafluoro-7,7,8,8-tetracyano-p-quinodimethane)
Matsushima, K
Ogaki, M
Naito, T
Inabe, T
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2000, 73 (10) : 2231 - 2235
[8] CRYSTAL-STRUCTURES FOR THE ELECTRON-DONOR DIBENZOTETRATHIAFULVALENE, DBTTF, AND ITS MIXED-STACK CHARGE-TRANSFER SALTS WITH THE ELECTRON-ACCEPTORS 7,7,8,8-TETRACYANO-P-QUINODIMETHANE, TCNQ, AND 2,5-DIFLUORO-7,7,8,8-TETRACYANO-P-QUINODIMETHANE, 2,5-TCNQF2
EMGE, TJ
WIYGUL, FM
CHAPPELL, JS
BLOCH, AN
FERRARIS, JP
COWAN, DO
KISTENMACHER, TJ
MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1982, 87 (1-2): : 137 - 161
[9] Synthesis and structure of the molecular complex between N-(N',N'-dimetbyiaminopropyl)phenothiazine hydrochloride and 7,7,8,8-tetracyano-p-quinodimethane (DAPP-TCNQ)
Rodriguez, JG
deLerma, JL
Perales, A
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 1996, 26 (01) : 53 - 58
[10] Theoretical Study of the Electronic Structure of [TCNQ]22- (TCNQ=7,7,8,8-Tetracyano-p-quinodimethane) Dimers and Their Intradimer, Long, Multicenter Bond in Solution and the Solid State
Garcia-Yoldi, Inigo
Miller, Joel S.
Novoa, Juan J.
JOURNAL OF PHYSICAL CHEMISTRY A, 2009, 113 (25): : 7124 - 7132

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