A PREPARATION OF N,N-BIS(TRIMETHYLSILYL)ALLENAMINES

被引：3
|
作者：
CUNICO, RF
KUAN, CP
机构：
[1] Department of Chemistry, Northern Illinois University, DeKalb
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1995年 / 487卷 / 1-2期
关键词：
SILICON; CARBANIONS; ALLENE; SILYL; AMINE; TRIMETHYLSILYL;
D O I：
10.1016/0022-328X(94)05068-M
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The lithium diisopropylamide-induced elimination of {2-[N,N-bis(trimethylsilyl)amino]alkenyl}(diethyl)phosphates affords 1-[N,N-bis(trimethylsilyl)amino]-1,2-alkadienes (''allenamines''). Conjugatively-substituted allenamines undergo further metalation under these eliminative conditions to form allenyl carbanions which may be trapped in situ by chlorotrimethylsilane to give 3-trimethylsilyl- or 3,3-bis(trimethylsilyl)-N, N-bis(trimethylsilyl)allenamines.
引用
收藏
页码：89 / 93
页数：5
相关论文
共 50 条
  • [1] A preparation of N,N-bis(trimethylsilyl)allenamines
    Cunico, R. F.
    Kuan, C. P.
    Journal of Organometallic Chemistry, 487 (1-2):
  • [2] PREPARATION OF ALIPHATIC N-TRIMETHYLSILYL KETIMINES AND N,N-BIS(TRIMETHYLSILYL) ENAMINES
    CHURAKOV, AM
    IOFFE, SL
    KHASAPOV, BN
    TARTAKOVSKII, VA
    BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE, 1978, 27 (01): : 113 - 119
  • [3] REACTION OF N,N-BIS(TRIMETHYLSILYL)ARYLSULFENYLAMINES AND N,N-BIS(TRIMETHYLSILYL)ARYLSULFENYLDIAMINES WITH SELENIUM TETRACHLORIDE
    ZIBAREV, AV
    ROGOZA, AV
    KONCHENKO, SN
    FEDOTOV, MA
    FURIN, GG
    ZHURNAL OBSHCHEI KHIMII, 1991, 61 (02): : 441 - 445
  • [4] N,N-BIS(TRIMETHYLSILYL) YNAMINES
    WEIGMANN, RH
    WURTHWEIN, EU
    TETRAHEDRON LETTERS, 1989, 30 (45) : 6147 - 6150
  • [5] N,N-BIS(TRIMETHYLSILYL)ENAMINES-STEREOSELECTIVE SYNTHESIS FROM N,N-BIS(TRIMETHYLSILYL)THIOFORMAMIDE
    WALTER, W
    LUKE, HW
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1977, 16 (08): : 535 - 536
  • [6] 9-Trimethylsilyl-N,N-bis(trimethylsilyl)adenine
    Gostevskii, B. A.
    Albanov, A. I.
    Lazareva, N. F.
    RUSSIAN CHEMICAL BULLETIN, 2024, 73 (03) : 743 - 745
  • [7] N,N-BIS(TRIMETHYLSILYL)-N',N-DIALKYLDIAMINOSULFANE
    RINNE, D
    BLASCHET.A
    CHEMIKER-ZEITUNG, 1974, 98 (09): : 456 - 457
  • [8] REACTION OF DIMETHYLCHLOROTHIOPHOSPHATE WITH N,N-BIS(TRIMETHYLSILYL)ACETAMIDE
    KIBARDINA, LK
    PUDOVIK, MA
    PUDOVIK, AN
    ZHURNAL OBSHCHEI KHIMII, 1986, 56 (08): : 1906 - 1906
  • [9] A NEW, CONVENIENT SYNTHESIS OF N,N-BIS[TRIMETHYLSILYL]ARENESULFONAMIDES
    ROMANENKO, VD
    TOVSTENKO, VI
    PIDVARKO, TV
    MARKOVSKI, LN
    SYNTHESIS-STUTTGART, 1981, (04): : 293 - 295
  • [10] Reactions of N,N,N'-tris(trimethylsilyl)lamide and N,N-bis (trimethylsilyl)-N'-tert-butylamide
    Rusilovets, A.I.
    Korendovich, I.V.
    Lis, T.
    Ukrainskij Khimicheskij Zhurnal, 2003, 69 (3-4): : 92 - 94
12345