4-[Amino(3-methylphenyl)methylidene]-2-(3-methylphenyl)-1H-imidazol-5(4H)-one ethanol hemisolvate

被引：0
|
作者：
Prabhuswamy, M. [1 ]
Kumar, S. Madan [1 ]
Muneer, C. P. [2 ]
Shafi, P. M. [2 ]
Lokanath, N. K. [1 ]
机构：
[1] Univ Mysore, Dept Studies Phys, Mysore 570006, Karnataka, India
[2] Calicut Univ, Dept Chem, Calicut 673635, Kerala, India
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2013年 / 69卷
关键词：
data-to-parameter ratio = 15.1; mean σ(C-C) = 0.004 Å; R factor = 0.070; single-crystal X-ray study; T = 300 K; wR factor = 0.227;
D O I：
10.1107/S160053681205163X
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title compound, C18H17N3O center dot 0.5C(2)H(5)OH, the dihedral angles between the central imidazole rings and the pendant benzene rings are 42.06 (15) and 2.01 (16)degrees in one asymmetric molecule and 47.91 (15) and 7.31 (14)degrees in the other. An intramolecular N-H center dot center dot center dot O hydrogen bond occurs in each imidazole molecule. In the crystal, the components are connected by O-H center dot center dot center dot N, N-H center dot center dot center dot O, C-H center dot center dot center dot O and NH center dot center dot center dot N hydrogen bonds. Weak aromatic pi-pi interactions also occur [ shortest centroid-centroid distance = 3.684 (3) (A) over circle].
引用
收藏
页码：O174 / +
页数：12
相关论文
共 50 条
  • [1] 4-n-butyl-3-(3-methylphenyl)-1H-1,2,4-triazol-5(4H)-one
    Akhtar, Tashfeen
    Hameed, Shahid
    Zia-ur-Rehman, Muhammad
    Bukhari, Tanveer Hussain
    Khan, Islamullah
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 : O1388 - U1322
  • [2] Fragrance material review on 2-(3-methylphenyl) ethanol
    Scognamiglio, J.
    Jones, L.
    Letizia, C. S.
    Api, A. M.
    FOOD AND CHEMICAL TOXICOLOGY, 2012, 50 : S173 - S175
  • [3] 4-(3-Methylphenyl)-3,5-di-2-pyridyl-4H-1,2,4-triazole
    Zhang, SP
    You, ZL
    Shao, SC
    Zhu, HL
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 : O27 - O28
  • [4] 4-(3-Methylphenyl)-3-phenyl-5-(2-pyridyl)-4H-1,2,4-triazole
    Gong, Xiaoning
    Wang, Zuoxiang
    Liu, Yan
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : O3214 - U1665
  • [5] 3-Acetyl-1-(3-methylphenyl)-5-phenyl-1H-pyrazole-4-carbonitrile
    Abdel-Aziz, Hatem A.
    Al-Obaid, Abdul-Rahman M.
    Ghabbour, Hazem A.
    Hemamalini, Madhukar
    Fun, Hoong-Kun
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2012, 68 : O485 - U1386
  • [6] N-{4-[(3-Methylphenyl)sulfamoyl]phenyl}benzamide
    Lahtinen, Manu
    Damodara, Jyothi
    Upadhyaya, Poornima
    Nonappa
    Kolehmainen, Erkki
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : O2866 - +
  • [7] N-{4-[(3-Methylphenyl)sulfamoyl]phenyl}acetamide
    Farrukh, Muhammad Akhyar
    Qureshi, Fahim Ashraf
    Adnan, Ahmad
    Turktekin, Sevim
    Akkurt, Mehmet
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2012, 68 : O437 - U944
  • [8] 4-Fluoro-2-[(3-methylphenyl)iminomethyl]phenol
    Brink, Alice
    Visser, Hendrik G.
    Roodt, Andreas
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : O1071 - +
  • [9] 1-Amino-2-anilino-4-(4-fluorobenzylidene)-1H-imidazol-5(4H)-one
    Zhang, Qian
    Jiao, Yuan-Hong
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2006, 62 : O3508 - O3509
  • [10] 2-(4-Chlorophenyl)-6-methyl-4-(3-methylphenyl)quinoline
    Prabhuswamy, M.
    Swaroop, T. R.
    Kumar, S. Madan
    Rangappa, K. S.
    Lokanath, N. K.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : O3250 - +
12345