KINETIC-SPECTROPHOTOMETRIC DETERMINATION OF THIOCYANATE BASED ON ITS INHIBITORY EFFECT ON THE OXIDATION OF PYROGALLOL RED BY BROMATE

被引：0

作者：

ENSAFI, AA ^{[1
]}

TAJEBAKHSHEARDAKANY, J ^{[1
]}

机构：

[1] ISFAHAN UNIV TECHNOL,COLL CHEM,ESFAHAN,IRAN

来源：

IRANIAN JOURNAL OF CHEMISTRY & CHEMICAL ENGINEERING-INTERNATIONAL ENGLISH EDITION | 1994年 / 13卷 / 02期

关键词：

KINETIC; THIOCYANATE; PYROGALLOL RED; BROMATE; OXIDATION; INHIBITORY EFFECT;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A kinetic spectrophotometric method for rapid measurement of thiocyanate in serum, urine and sewage,wafer with no need for removed of interfering substances is described. The method is based on the inhibitory effect of thiocyanate on the oxidation of pyrogallol red by bromate and nitrite which is monitored at 467nm. The variables affecting the rate of the reaction were investigated and the optimum conditions were established. Thiocyanate can be measured in the range of 0.010-0.500 mu g/mL with a limit of detection of 0.001 mu g/mL. The relative standard deviation for ten replicate determination of 0.025 mu g/mL of thiocyanate is 1.5%.

引用

页码：97 / 103

页数：7

共 50 条

[1] Kinetic Spectrophotometric Determination of Thiocyanate Based on Its Inhibitory Effect on the Oxidation of Methyl Red by Bromate
Jahanbakhsh Ghasemi
Reza Amini
Abbas Afkhami
[J]. Analytical Sciences, 2001, 17 : 435 - 438
[2] Kinetic spectrophotometric determination of thiocyanate based on its inhibitory effect on the oxidation of methyl red by bromate
Ghasemi, J
Amini, R
Afkhami, A
[J]. ANALYTICAL SCIENCES, 2001, 17 (03) : 435 - 437
[3] KINETIC-SPECTROPHOTOMETRIC DETERMINATION OF MANGANESE AND VANADIUM + MANGANESE BY OXIDATION OF PYROGALLOL RED
SEVILLANOCABEZA, A
MEDINAESCRICHE, J
DELAGUARDIACIRUGEDA, M
[J]. ANALYST, 1984, 109 (10) : 1303 - 1307
[4] SPECTROPHOTOMETRIC DETERMINATION OF BROMATE BY THE OXIDATION OF PYROGALLOL RED
MEDINAESCRICHE, J
SEVILLANOCABEZA, A
MARTINPENELLA, M
LLOBATESTELLES, M
[J]. ANALYST, 1985, 110 (12) : 1467 - 1471
[5] Kinetic-spectrophotometric determination of palladium in hydrogenation catalyst by its catalytic effect on the oxidation of pyrogallol red by hydrogen peroxide
Ensafi, AA
Keyvanfard, M
[J]. SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2002, 58 (08) : 1567 - 1572
[6] Kinetic-spectrophotometric determination of trace quantities of thiocyanate based on its Landolt effect on the reaction of bromate with hydrochloric acid
Madrakian, T
Esmaeili, A
Abdolmaleki, A
[J]. JOURNAL OF ANALYTICAL CHEMISTRY, 2004, 59 (01) : 28 - 32
[7] Kinetic-spectrophotometric determination of trace quantities of thiocyanate based on its landolt effect on the reaction of bromate with hydrochloric acid
Madrakian T.
Esmaeili A.
Abdolmaleki A.
[J]. Journal of Analytical Chemistry, 2004, 59 (1) : 28 - 32
[8] KINETIC-SPECTROPHOTOMETRIC DETERMINATION OF TRACES OF OSMIUM BY ITS CATALYTIC EFFECT ON THE OXIDATION OF PYROGALLOL RED BY HYDROGEN-PEROXIDE
ENSAFI, AA
REZAEI, B
[J]. ANALYTICAL LETTERS, 1993, 26 (08) : 1771 - 1785
[9] KINETIC-SPECTROPHOTOMETRIC DETERMINATION OF NITRITE BY ITS ACCELERATING EFFECT ON THE OXIDATION OF TOLUIDINE BLUE BY BROMATE
Moldovan, Zenovia
[J]. REVUE ROUMAINE DE CHIMIE, 2011, 56 (01) : 39 - +
[10] Kinetic-spectrophotometric determination of trace amounts of resorcinol based on its inhibitory effect on the formaldehyde catalyzed reaction between bromate and neutral red
Parham, H
Pourreza, N
Cheraghi, S
[J]. ANALYTICAL LETTERS, 1999, 32 (09) : 1917 - 1926

← 1 2 3 4 5 →