STEREOSELECTIVE ALPHA-ALKYLATION OF CARBONYL-COMPOUNDS USING TRICARBONYLCHROMIUM-COMPLEXED BENZYL ACETATES

被引:11
|
作者
REETZ, MT
SAUERWALD, M
机构
[1] Fachbereich Chemie der Universität, 3550 Marburg, Hans-Meerwein-Strasse
关键词
D O I
10.1016/0022-328X(90)85221-J
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Secondary benzyl acetates complexed by Cr(CO)3 react 100% stereoselectively with enolsilanes in the presence of ZnCl2 in a process which amounts to α-alkylation of carbonyl compounds. © 1990.
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页码:121 / 128
页数:8
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