SYNTHESIS, SPECTROSCOPIC AND STRUCTURAL CHARACTERIZATION OF PERIODATE COMPLEXES OF IRON(III)

被引：6
|
作者：
JONES, EM
LEVASON, W
OLDROYD, RD
WEBSTER, M
THOMAS, M
HUTCHINGS, J
机构：
[1] UNIV SOUTHAMPTON,DEPT CHEM,SOUTHAMPTON SO17 1BJ,HANTS,ENGLAND
[2] UNIV LIVERPOOL,DEPT PHYS,OLIVER LODGE LAB,LIVERPOOL L69 3BX,MERSEYSIDE,ENGLAND
来源：
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1995年 / 20期
关键词：
D O I：
10.1039/dt9950003367
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reaction of Fe(NO3)(3) . 9H(2)O with NalO(4) in aqueous acid solution gave brown [Fe(4)l(3)O(24)H(15)] and subsequent reaction with concentrated alkalis formed M(n)[Fe(4)l(3)O(24)H(15-n)] (M = Li, Na, Kr Rb or Cs). The crystal structure of K6Na2[Fe(4)l(3)O(24)H(7)]. 14H(2)O has been determined and shown to contain an Anderson-type anion composed of seven edge-linked octahedra. In the crystal, studied a central FeO6 group is surrounded by six disordered FeO6 and IO6 groups. All the prepared salts have been shown to contain a similar anion based upon spectroscopic data. iron and iodine K-edge extended X-ray absorption fine structure data, and the Fe-57 Mossbauer spectra.
引用
收藏
页码：3367 / 3373
页数：7
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