PROGRESS IN THE TOTAL SYNTHESIS OF BREVETOXINS

被引：0
|
作者：
REDDY, KR
SKOKOTAS, G
NICOLAOU, KC
机构：
[1] Scripps Res Inst, DEPT CHEM, 10666 N TORREY PINES RD, LA JOLLA, CA 92037 USA
[2] UNIV CALIF SAN DIEGO, DEPT CHEM, LA JOLLA, CA 92093 USA
来源：
GAZZETTA CHIMICA ITALIANA | 1993年 / 123卷 / 06期
关键词：
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A number of synthetic methods for the construction of cyclic ethers of the type found in the brevetoxins are described. These methods include cyclization reactions involving hydroxy epoxides, hydroxy dithioketals and hydroxy ketones, bridging of dithionolactones and dithionoesters, and nucleophilic additions to thionolactones. Application of this technology to the total synthesis of hemibrevetoxin B is also discussed.
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页码：337 / 341
页数：5
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