Metallic complexes supported on functionalized MCM-48 in catalytic reactions (Part I). 1-hexene hydrogenation with Re-2(CO)(8)(mu-dffm) complex

被引：0

作者：

Vielma, Joel E. ^{[1
]}

Contreras, Ricardo R. ^{[1
]}

Fontal, Bernardo ^{[1
]}

Reyes, Marisela ^{[1
]}

Bellandi, Fernando ^{[1
]}

Fonseca, Yuraima ^{[1
]}

Araque, Cesar ^{[1
]}

Parra, Maria ^{[1
]}

Diaz, Juan C. ^{[2
]}

机构：

[1] Univ Los Andes, Fac Ciencias, Lab Organometal, Merida 5101, Venezuela

[2] Univ Los Andes, Nucleo Univ Rafael Rangel, Dept Biol & Quim, Trujillo 3102, Venezuela

来源：

CIENCIA E INGENIERIA | 2014年 / 35卷 / 02期

关键词：

Rhenium complexes; hybrid catalysts; hydrogenation;

D O I：

暂无

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Re(CO)(8)(mu-dffm) (dffm=diphenilphosphinemethane) was supportted on funtionalized MCM-48 using a post-synthesis method with [3-(2-aminoethylamino)proyil] and trimethoxysilane as anchoring and passivation ligands respectively. The catalyst obtained was characterized with infrared spectroscopy (IR-FT), mass spectrometry (MS), thermogravimetric analysis (TGA), nitrogen adsorption-desorption and scanning electron microscopy and energy dispersive X-ray analysis (SEM/EDX). Catalysts were used on 1-hexene hydrogenation reactions and show high conversion rates and were reused up to five times without great loss of catalytic activity.

引用

页码：103 / 111

页数：9

共 5 条

[1] Metallic complexes supported on functionalized MCM-48 in catalytic reactions (Part II). 1-hexene hydroformilation with Mo(CO)(2)(NC5H10)(4) complex
Vielma, Joel E.
Contreras, Richards R.
Fontal, Bernardo
Reyes, Marisela
Bellandi, Fernando
Fonseca, Yuraima
Araque, Cesar
Parra, Maria
Cardozo, Eduardo
CIENCIA E INGENIERIA, 2015, 36 (01): : 31 - 39
[2] Reactions of co-ordinated ligands. Part 40. Synthesis, structure, and reactivity of dirhenium -mu-allylidene complexes; crystal structures of [Re-2(mu-sigma:eta(3)-CHCHCME2)(CO)(8)] and [Re-2(mu-sigma-eta(3)-CHCHCMe2)(CO)(9)]
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ORPEN, AG
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JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1987, (06): : 1313 - 1318
[3] Influence of the pressure and the temperature in the reaction of hydroformylation of the 1-hexene in biphasic media in continuous running with the catalytic complex [(mu-Pz)(CO)(TPPTS)Rh](2) (I)
Guanipa, Victor
Lujano, Ramon
Bruss, Arnoldo
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INGENIERIA UC, 2006, 13 (01): : 15 - 25
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JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1988, 356 (01) : 93 - 104
[5] REACTIONS OF THE POLYHYDRIDES RE2H8(PPH3)4 AND REH7(PPH3)2 WITH ACETIC-ACID ACETIC-ANHYDRIDE - ISOLATION AND CHARACTERIZATION OF THE RHENIUM(I) CARBONYL-COMPLEXES RE(O2CCH3)(CO)1+X(PPH3)3-X (X = 0, 1) AND THE HOMOLEPTIC DIRHENIUM(III) CARBOXYLATE COMPLEX RE2(MU-O2CCH3)4(O2CCH3)2
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