RING-OPENING POLYMERIZATION OF 2-PHENYL-4,7-DIOXASPIRO[2.4]HEPTANE

被引：1
|
作者：
RASOUL, HAA
BEAM, JR
MCKINNEY, MA
AIANI, KE
机构：
[1] SC JOHNSON & SON INC,LOUIS LAB,RACINE,WI 53403
[2] MARQUETTE UNIV,DEPT CHEM,MILWAUKEE,WI 53233
来源：
MAKROMOLEKULARE CHEMIE-MACROMOLECULAR SYMPOSIA | 1991年 / 42-3卷
关键词：
D O I：
10.1002/masy.19910420117
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
1-Phenyl-4,7-dioxaspiro[2.4]heptane (1) was spontaneously copolymerized in bulk at 70-degrees-C with maleic and itaconic anhydride to give 1:1 alternating copolymer. Both the cyclopropyl and dioxapentyl rings were observed to open during the propagation. Copolymer yields, compositions and molecular weights are similar regardless of the presence of free radical initiator or inhibitor. A propagation mechanism via zwitterionic addition is suggested. Only homopolymers of styrene and acrylonitrile were isolated when these monomers were heated with 1 in bulk at 70-degrees-C in the presence or absence of AIBN. The cationic ring-opening oligomerization of 1 is also discussed.
引用
收藏
页码：205 / 217
页数：13
相关论文
共 50 条
  • [1] RING-OPENING POLYMERIZATION OF 2-PHENYL-4,7-DIOXASPIRO[2.4] HEPTANE
    RASOUL, HAA
    MCKINNEY, MA
    AIANI, KE
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1990, 199 : 48 - POLY
  • [2] THE REACTION OF "2-PHENYL-4,7-DIOXASPIRO[2.4]HEPTANE WITH ELECTROPHILES
    MCKINNEY, MA
    PINTO, MS
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1985, 190 (SEP): : 79 - ORN
  • [3] Continuous flow ring-opening polymerization and ring-opening metathesis polymerization
    Liu, Yihuan
    Ou, Shi
    Wu, Jiaqi
    Zhao, Rongji
    Hou, Ruixiang
    Li, Xiaomin
    Sun, Yongxiang
    Li, Yuguang
    Hu, Xin
    Zhu, Ning
    Guo, Kai
    EUROPEAN POLYMER JOURNAL, 2024, 216
  • [4] STEREOCHEMISTRY OF RING-OPENING POLYMERIZATION OF "2-METHYL-7-OXABICYCLO[2.2.1]HEPTANE
    SAEGUSA, T
    FUJII, H
    MOTOI, M
    MATSUMOT.S
    MACROMOLECULES, 1972, 5 (03) : 233 - &
  • [5] Ring-opening polymerization
    Penczek, Stanislaw
    Pretula, Julia
    Slomkowski, Stanislaw
    CHEMISTRY TEACHER INTERNATIONAL, 2021, 3 (02) : 33 - 57
  • [6] EXPLORATORY RING-OPENING POLYMERIZATION .5. RADICAL RING-OPENING AND CATIONIC POLYMERIZATION OF 2-METHYLENE-4-PHENYL-1,3-DIOXOLANE
    CHO, I
    GONG, MS
    JOURNAL OF POLYMER SCIENCE PART C-POLYMER LETTERS, 1982, 20 (07) : 361 - 364
  • [7] EXPLORATORY RING-OPENING POLYMERIZATION .8. RADICAL RING-OPENING POLYMERIZATION OF 2-PHENYL-3-VINYLOXIRANE - A C-C BOND SCISSION POLYMERIZATION OF THE EPOXIDE RING
    CHO, I
    KIM, JB
    JOURNAL OF POLYMER SCIENCE PART C-POLYMER LETTERS, 1983, 21 (06) : 433 - 436
  • [8] EXPLORATORY RING-OPENING POLYMERIZATION - RING-OPENING POLYMERIZATION OF VINYLKETENE CYCLIC ACETAL
    CHO, I
    KIM, SK
    JOURNAL OF POLYMER SCIENCE PART C-POLYMER LETTERS, 1990, 28 (13) : 417 - 421
  • [9] Synthesis and cationic polymerization of 2-phenyl-1,6-dioxaspiro[4.6]undecane. A novel expandable monomer undergoing cationic double ring-opening polymerization
    Fukuchi, I
    Sanda, F
    Endo, T
    MACROMOLECULES, 2001, 34 (13) : 4296 - 4298
  • [10] PREPARATION AND RING-OPENING POLYMERIZATION OF 2-TERT-BUTYL-7-OXABICYCLO[2.2.1]HEPTANE
    SAEGUSA, T
    MOTOI, M
    SUDA, H
    MACROMOLECULES, 1976, 9 (02) : 231 - 234
12345