ANALYTICAL PERFORMANCES OF LIPOPHILIC DIAMIDES BASED ALKALINE-EARTH ION-SELECTIVE ELECTRODES

被引：23
|
作者：
TOTH, K
LINDNER, E
HORVATH, M
JENEY, J
PUNGOR, E
BITTER, I
AGAI, B
TOKE, L
机构：
[1] TECH UNIV BUDAPEST,INST GEN & ANALYT CHEM,GELLERT TER 4,H-1111 BUDAPEST,HUNGARY
[2] TECH UNIV BUDAPEST,DEPT ORGAN CHEM TECHNOL,H-1111 BUDAPEST,HUNGARY
来源：
ELECTROANALYSIS | 1993年 / 5卷 / 9-10期
关键词：
ALKALINE EARTH IONS; LIPOPHILIC DIAMIDES; ION SELECTIVE ELECTRODES; POTENTIOMETRY; DIAMIDES;
D O I：
10.1002/elan.1140050911
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
Based on complex chemical considerations, lipophilic diamide derivatives have been designed and synthesized as ionophores for liquid membrane electrodes. The structure-selectivity studies revealed that the majority of the ligands exhibit calcium ion selectivity except the compound bis-N,N-dicyclohexyl-malonamide. The latter has an almost equal selectivity for Ca2+ and Mg2+ and sufficiently rejects sodium ions, thus it lends itself to water hardness measurements.
引用
收藏
页码：781 / 790
页数：10
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