DIFFUSION-CONTROLLED REACTIONS WITH POLYMERS

被引:26
|
作者
BURLATSKY, SF
OSHANIN, GS
机构
[1] Institute of Chemical Physics, USSR Academy of Sciences, 117334 Moscow, V-334
关键词
D O I
10.1016/0375-9601(90)90278-V
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
We study the probabilities for the existence of chain-free cavities in solutions with various volume fractions of polymer and derive the exact (for Gaussian coils) and approximate expressions (for swollen coils, rod-like molecules and branched polymers). On the basis of these distributions we obtain the explicit dependences describing trapping kinetics in polymer systems. © 1990.
引用
收藏
页码:61 / 65
页数:5
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