EXCESS-ENTHALPIES IN THE BINARY-SYSTEMS WATER-HYDRAZINE, WATER-METHYLHYDRAZINE AND WATER-1,1-DIMETHYLHYDRAZINE - DETERMINATION AND MODELING IN RELATION TO THE STRUCTURE OF THE LIQUID-PHASE

被引：2

作者：

FERRIOL, M ^{[1
]}

LAACHACH, A ^{[1
]}

COHENADAD, MT ^{[1
]}

THOUREY, J ^{[1
]}

机构：

[1] INSA,CNRS,URA 116,THERMOCHIM MINERALE LAB,VILLEURBANNE,FRANCE

来源：

FLUID PHASE EQUILIBRIA | 1993年 / 91卷 / 01期

关键词：

EXPERIMENTS; THEORY; DATA; EXCESS FUNCTIONS; EXCESS ENTHALPIES; ASSOCIATION;

D O I：

10.1016/0378-3812(93)85082-W

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Excess enthalpies of the binary mixtures of water and hydrazine, N2H4 or methylhydrazine, CH3NHNH2 or 1,1-dimethylhydrazine, (CH3)2NNH2 are determined at 278.15 and 293.16 K. In the three cases, a chemical association model involving two hydrates (mono and tri- or tetrahydrate), a dimer for alkylhydrazine and assuming an ideal behavior of all species present, gives a good representation of the mixing properties of these mixtures.

引用

页码：101 / 112

页数：12

共 6 条

[1] SOLID-LIQUID EQUILIBRIA AND MODELING OF THE BINARY-SYSTEMS WATER-METHYLHYDRAZINE AND WATER-1,1-DIMETHYLHYDRAZINE
FERRIOL, M
GIUDICE, M
COHENADAD, MT
FOULON, M
GUINET, Y
LEBRUN, N
MULLER, M
BUREAU, JC
ELWIDADI, T
FLUID PHASE EQUILIBRIA, 1993, 86 : 187 - 200
[2] VAPOR-LIQUID-EQUILIBRIA IN THE BINARY-SYSTEMS WATER METHYLHYDRAZINE AND WATER-1,1-DIMETHYLHYDRAZINE - THERMODYNAMIC MODELING IN RELATION TO THE STRUCTURE OF THE LIQUID-PHASE
FERRIOL, M
LAACHACH, A
COHENADAD, MT
GETZEN, FW
JORAT, L
NOYEL, G
HUCK, J
BUREAU, JC
FLUID PHASE EQUILIBRIA, 1992, 71 (03) : 287 - 299
[3] DENSITIES, MOLAR VOLUMES AND VISCOSITIES IN THE SYSTEMS WATER HYDRAZINE, WATER METHYLHYDRAZINE AND WATER-1,1-DIMETHYLHYDRAZINE
LAACHACH, A
FERRIOL, M
COHENADAD, MT
HUCK, J
JORAT, L
NOYEL, G
GETZEN, FW
BUREAU, JC
FLUID PHASE EQUILIBRIA, 1992, 71 (03) : 301 - 312
[4] SOLID + LIQUID-PHASE EQUILIBRIA, EXCESS-ENTHALPIES, AND ENTHALPIES OF FUSION IN (2,3-DIMETHYL-2,3-BUTANEDIOL + WATER)
PRIEST, JG
WOOLLEY, EM
OTT, JB
GOATES, JR
JOURNAL OF CHEMICAL THERMODYNAMICS, 1983, 15 (04): : 357 - 366
[5] LIQUID-PHASE EXCESS-ENTHALPIES FOR THE BINARY-SYSTEMS OF 1,3-DIOXOLANE WITH NORMAL-PENTANE, 3-METHYLPENTANE, OR METHYLCYCLOPENTANE
COMELLI, F
FRANCESCONI, R
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1990, 35 (03): : 283 - 284
[6] EXPERIMENTAL-DETERMINATION OF THE 2-PHASE (LIQUID AND VAPOR) REGION IN WATER ALKALI CHLORIDE BINARY-SYSTEMS AT 500-DEGREES-C AND 600-DEGREES-C USING SYNTHETIC FLUID INCLUSIONS
DUBOIS, M
WEISBROD, A
SHTUKA, A
CHEMICAL GEOLOGY, 1994, 115 (3-4) : 227 - 238

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