NOVEL CRYSTAL-STRUCTURE OF YTTERBIUM(II)-BENZOPHENONE DIANION COMPLEX AND ITS REACTION WITH 2,6-DI-TERT-BUTYL-4-METHYLPHENOL

被引：71
|
作者：
HOU, ZM
YAMAZAKI, H
KOBAYASHI, K
FUJIWARA, Y
TANIGUCHI, H
机构：
[1] HIROSHIMA UNIV,FAC ENGN,DEPT APPL CHEM,HIROSHIMA 724,JAPAN
[2] KYUSHU UNIV,FAC ENGN,DEPT CHEM SCI & TECHNOL,FUKUOKA 812,JAPAN
来源：
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 09期
关键词：
D O I：
10.1039/c39920000722
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Treatment of 1 equiv. of Yb metal with benzophenone in tetrahydrofuran-hexamethylphosphoramide (hmpa) gives a Yb(II)-benzophenone dianion complex, [{Yb(OCPh2)(hmpa)2}2] 1 which on treatment with 2,6-di-tert-butyl-4-methylphenol produces [Yb(OC6H2But2-2,6-Me-4)2(hmpa)2] 2; both 1 and 2 are structurally characterized by X-ray crystallography.
引用
收藏
页码：722 / 724
页数：3
相关论文
共 50 条
  • [1] THE OXIDATION OF 2,6-DI-TERT-BUTYL-4-METHYLPHENOL
    YOHE, GR
    DUNBAR, JE
    PEDROTTI, RL
    SCHEIDT, FM
    LEE, FGH
    SMITH, EC
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 1956, 21 (11): : 1289 - 1292
  • [2] STRUCTURAL DIAGRAMS OF 4-METHYLPHENOL-6-TERT-BUTYL-4-METHYLPHENOL, 4-METHYLPHENOL-2,6-DI-TERT-BUTYL-4-METHYLPHENOL AND 6-TERT-BUTYL-4-METHYLPHENOL-2,6-DI-TERT-BUTYL-4-METHYLPHENOL SYSTEMS
    GORODETSKII, ET
    [J]. IZVESTIYA VYSSHIKH UCHEBNYKH ZAVEDENII KHIMIYA I KHIMICHESKAYA TEKHNOLOGIYA, 1981, 24 (03): : 383 - 384
  • [3] PHOTOCHEMICAL PROCESSES OF 2,6-DI-TERT-BUTYL-4-METHYLPHENOL
    NOWAKOWSKA, M
    KOWAL, J
    [J]. EUROPEAN POLYMER JOURNAL, 1980, 16 (07) : 615 - 618
  • [4] ANODIC PYRIDINATION OF 2,6-DI-TERT-BUTYL-4-METHYLPHENOL
    OHMORI, H
    UEDA, C
    TOKUNO, Y
    MASUI, M
    [J]. CHEMICAL & PHARMACEUTICAL BULLETIN, 1982, 30 (10) : 3786 - 3790
  • [5] 2,6-DI-TERT-BUTYL-4-METHYLPHENOL AS A GASOLINE ANTIOXIDANT
    JONES, MCK
    JONES, AR
    STRICKLAND, BR
    [J]. INDUSTRIAL AND ENGINEERING CHEMISTRY, 1952, 44 (11): : 2721 - 2725
  • [6] DEALKYLATION OF 2,6-DI-TERT-BUTYL-4-METHYLPHENOL ON HYDROSULFATES
    GORODETSKII, ET
    TRENDOVATSKII, PI
    LARKOVA, VM
    [J]. KINETICS AND CATALYSIS, 1989, 30 (01) : 115 - 118
  • [7] REACTION OF TERT-BUTOXY RADICALS WITH 2,6-DI-TERT-BUTYL-4-METHYLPHENOL AND 2,6-DI-TERT-BUTYLPHENOL
    INGOLD, KU
    [J]. CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1963, 41 (11): : 2807 - &
  • [8] Synthesis of organophosphorus derivatives of 2,6-di-tert-butyl-4-methylphenol
    Prishchenko, Andrey A.
    Livantsov, Mikhail V.
    Novikova, Olga P.
    Livantsova, Ludmila I.
    Milaeva, Elena R.
    [J]. HETEROATOM CHEMISTRY, 2008, 19 (05) : 490 - 494
  • [9] Interaction of the antioxidant 2,6-di-tert-butyl-4-methylphenol with photosystem II of chloroplasts
    Samuilov, VD
    Barsky, EL
    Samuilov, FD
    [J]. BIOCHEMISTRY-MOSCOW, 1995, 60 (11) : 1417 - 1421
  • [10] Synthesis of phosphorus derivatives of 2,6-di-tert-butyl-4-methylphenol
    Prishchenko, A. A.
    Livantsov, M. V.
    Novikova, O. P.
    Livantsova, L. I.
    Shpakovskii, D. B.
    Milaeva, E. R.
    [J]. RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2006, 76 (11) : 1753 - 1756
12345