MULTISTEP REDOX SYSTEMS .57. QUATERNARY-SALTS OF PYRIDYL-SUBSTITUTED 1,3,5-TRIAZINES - A NEW CLASS OF 2-STEP TO 4-STEP REVERSIBLE REDOX SYSTEMS

被引：0

作者：

GRIES, WK ^{[1
]}

GUNTHER, E ^{[1
]}

HUNIG, S ^{[1
]}

机构：

[1] UNIV WURZBURG,INST ORGAN CHEM,W-8700 WURZBURG,GERMANY

来源：

LIEBIGS ANNALEN DER CHEMIE | 1991年 / 10期

关键词：

REDOX SYSTEMS; 1,3,5-TRIAZINES; PYRIDINIUM SALTS;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis of 1,3,5-triazines 3-5 a-e substituted by one to three 4-pyridinium rings [N-substituents Me, Et, Benzyl, CH2C(O)NMe2, CH2CO2C(O)OEt] is described. According to voltammetric data 3-5 constitute a new type of redox systems with reversible electron transfer in two to four separate steps. Reduction by zinc or sodium amalgam in acetonitrile produces coloured stable solutions of radicals (SEM).

引用

页码：1021 / 1028

页数：8

共 11 条

[1] MULTISTEP REVERSIBLE REDOX SYSTEMS .34. POLYENES AS 4-STEP REDOX SYSTEMS - SYNTHESIS AND SPECTROSCOPY
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[2] 2-STEP REDOX SYSTEMS .31. PYRIDYL-SUBSTITUTED CYCLOBUTANES - REVERSIBLE CONVERSION OF 1,3-BISMETHYLENECYCLOBUTANES INTO BICYCLO[1.1.0]BUTANES
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[3] MULTISTEP REVERSIBLE REDOX SYSTEMS .57. N,N'-DICYANOQUINONEDIIMINES - A NEW CLASS OF COMPOUNDS .2. COMPARISON OF REDOX PROPERTIES WITH THOSE OF QUINONES AND TETRACYANOQUINODIMETHANES
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[5] 2-STEP REDOX SYSTEMS .17. SYNTHESIS OF VINYLOGOUS AND AZAVINYLOGOUS REDOX SYSTEMS WITH 1,3,3-TRIMETHYLINDOLENINE END GROUPS
HUNIG, S
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[6] 2 STEP REDOX SYSTEMS .12. SYNTHESIS AND POLAROGRAPHY OF QUATERNARY-SALTS DERIVED FROM PHENANTHROLINES - 2,7-DIAZAPYRENE AND FROM DIAZONIAPENTAPHENES
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[J]. ANNALEN DER CHEMIE-JUSTUS LIEBIG, 1973, 2 : 339 - 358
[7] 2-STEP REDOX SYSTEMS, .18. POLAROGRAPHY AND ESR SPECTROSCOPY OF VINYLOGOUS AND AZAVINYLOGOUS REDOX SYSTEMS WITH 1,3,3-TRIMETHYLINDOLENINE END GROUPS
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[8] MULTISTEP REVERSIBLE REDOX SYSTEMS .44. SYNTHESIS, SPECTROSCOPIC AND ELECTROCHEMICAL PROPERTIES OF 1-SUBSTITUTED 4-(DIMETHYLAMINO)PYRIDINIUM SALTS
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[9] 2-STEP REDOX SYSTEMS .30. SPECTROSCOPIC AND ELECTROCHEMICAL PROPERTIES OF N-SUBSTITUTED 1,4-DIHYDRO-4,4-DIMETHYLPYRIDINES
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[10] MULTISTEP REVERSIBLE REDOX SYSTEMS .42. [2+2]PHOTOCYCLOADDITIONS OF ALPHA-STYRYLPYRYLIUM SALTS TO 4,4'-(1,3-CYCLOBUTANEDIYL)BIS(PYRYLIUM) SALTS AND THEIR THERMAL AND BASE-INDUCED CYCLOREVERSIONS
HESSE, K
HUNIG, S
[J]. LIEBIGS ANNALEN DER CHEMIE, 1985, (04): : 715 - 739

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