STEREOSELECTIVE REDUCTION OF (R,S)-[(ETA-5-C5H5)FE(CO)(PPH3)(=COCH2CH2CME2)]+ AND COMPLETE EPIMERIZATION OF THE KINETIC (RR,SS)-DIASTEREOISOMER TO THE THERMODYNAMIC (RS,SR)-DIASTEREOISOMER OF THE PRODUCT [(ETA-5-C5H5)FE(CO)(PPH3)(C(H)OCH2CH2CME2)]

被引：21

作者：

AYSCOUGH, AP ^{[1
]}

DAVIES, SG ^{[1
]}

机构：

[1] DYSON PERRINS LAB,S PARKS RD,OXFORD OX1 3QY,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1986年 / 22期

关键词：

D O I：

10.1039/c39860001648

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

引用

页码：1648 / 1649

页数：2

共 50 条

[1] FRAGMENTATION OF (ETA-5-C5H5)FE(CO)(PPH3)(COCH2COR) COMPLEXES TO THE CATION [(ETA-5-C5H5)FE(CO)2(PPH3)]+
DAVIES, SG
WATTS, O
AKTOGU, N
FELKIN, H
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1983, 243 (03) : C51 - C53
[2] SELF-RECOGNITION BY THE IRON CHIRAL AUXILIARY [(ETA-5-C5H5)FE(CO)(PPH3)] IN THE FORMATION OF (RR,SS)-[(ETA-5-C5H5)FE(CO)(PPH3)COCH2]2CH2
BODWELL, GJ
DAVIES, SG
PRESTON, SC
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1991, 402 (03) : C56 - C58
[3] CONFORMATION ANALYSIS OF COMPOUNDS OF THE TYPE [FE(ETA-5-C5H5)(CO)(PPH3)(CH2ALKYL)], "[FE(ETA-5-C5H5)(CO)(PPH3)(CH2ARYL)] - REPLY
SEEMAN, JI
DAVIES, SG
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1985, (12): : 2692 - 2693
[4] CONFORMATION ANALYSIS OF COMPOUNDS OF THE TYPE [FE(ETA-5-C5H5)(CO)(PPH3)-(CH2ALKYL)], [FE(ETA-5-C5H5)(CO)(PPH3)(CH2ARYL) - COMMENT
CAMERON, AD
BAIRD, MC
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1985, (12): : 2691 - 2692
[5] BIMETALLIC ORGANOTRANSITION-METAL TAUTOMERS OF A CHIRAL ENOLATE - PREPARATION OF [(ETA-5-C5H5)FE(CO)(PPH3)C(CH2)O(CL)ZR(ETA-5-C5H5)2] AND [(ETA-5-C5H5)FE(CO)(PPH3)C(O)CH2AU(PPH3)] - X-RAY CRYSTAL-STRUCTURE OF [(ETA-5-C5H5)FE(CO)(PPH3)C(CH2)O(CL)ZR(ETA-5-C5H5)2]
WEINSTOCK, I
FLORIANI, C
CHIESIVILLA, A
GUASTINI, C
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (26) : 8298 - 8299
[6] STEREOSPECIFICITY OF THE REARRANGEMENT OF THE ALPHA-ALKOXY IRON ACYL [(ETA-5-C5H5)FE(CO)(PPH3)COCH2OCH2PH] TO THE ALPHA-METALLA-ESTER [(ETA-5-C5H5)FE(CO)(PPH3)CH2CO2CH2PH]
DAVIES, SG
WILLS, M
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (21) : 1647 - 1648
[7] STEREOSELECTIVE ADDITIONS TO THE ALKOXYCARBENE CATIONS [ETA-5-C5H5)FE(CO)(PPH3)(=CHOME)], [ETA-5-C5H5)FE(CO)(PPH3)(=CETOME)]
BAIRD, GJ
DAVIES, SG
MABERLY, TR
[J]. ORGANOMETALLICS, 1984, 3 (11) : 1764 - 1765
[8] ELECTRON-RICH CATIONS - PREPARATION AND HYDRIDE REDUCTIONS OF THE CATIONS [FE(ETA-5-C5H5)(PHP(CH2CH2PPH2)2)]+, [FE(ETA-5-C5H5)(MEC(CH2PPH2)3)]+, AND [FE(ETA-5-C5H5)(C(CH2PPH2)4)]+
DAVIES, SG
SIMPSON, SJ
FELKIN, H
TADJ, F
WATTS, O
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1983, (05): : 981 - 985
[9] CHIRAL DISCRIMINATION IN THE REACTION OF THE ENOLATE [(ETA-5-C5H5)FE(CO)(PPH3)(COCH2)]-LI+ WITH MONOSUBSTITUTED EPOXIDES - X-RAY CRYSTAL-STRUCTURE OF (RS,SR)-[(ETA-5-C5H5)FE(CO)(PPH3)(COCH2CH2CH(OH)ME)]
BROWN, SL
DAVIES, SG
WARNER, P
JONES, RH
PROUT, K
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1985, (20) : 1446 - 1447
[10] STEREOSELECTIVE ELABORATION OF THE ACYL LIGAND IN (ETA-5-C5H5)FE(CO)(PPH3)(COCH2R) VIA THE ALKYLATION OF THE ANIONS "[(ETA-5-C5H5)FE(CO)(PPH3)(COCHR)]LI (R = ME, ET)
BAIRD, GJ
DAVIES, SG
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1983, 248 (01) : C1 - C3

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