Experimental Determination of the Molar Volume and Derivation of the Expansion Coefficient, Entropy Change on Compression, Compressibility, and First-Sound Velocity for Liquid He-3 from 35 to 1200 mK and from the Saturation Pressure to 24 atm

被引:46
|
作者
Abraham, Bernard M. [1 ]
Osborne, Darrell W. [1 ]
机构
[1] Argonne Natl Lab, Div Chem, Argonne, IL 60439 USA
关键词
D O I
10.1007/BF00629709
中图分类号
O59 [应用物理学];
学科分类号
摘要
The molar volume of liquid He-3, V(P, T), was determined from measurements of the dielectric constant over the temperature range 35-1200 mK and from the vapor pressure to 24 arm. Analytical expressions were fitted to the molar volumes in order to calculate the isobaric expansion coefficient alpha(p), the isothermal compressibility kappa(T), and the first-sound velocity c(1); the expansion coefficient was integrated numerically to arrive at the entropy change on compression. Values of V(P, T) and the derived quantities are presented in tabular form at even temperatures and pressures. From this work it was found that V(0, 0)=36.873 +/- 0.015 cm(3)/mole and that c(1)(0,0) = 178.4 m/sec, about 2.5% lower than the presently accepted value of 183.4 m/sec.
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页码:335 / 352
页数:18
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