REACTIVITY OF CP-ASTERISK-RU+ WITH ACYCLIC UNSATURATED-HYDROCARBONS - A NOVEL CATALYTIC CARBON CARBON BOND ACTIVATION REACTION

被引：18

作者：

CARRENO, R

CHAUDRET, B

LABROUE, D

SABOETIENNE, S

机构：

[1] UNIV PAUL SABATIER,CNRS,UPR 8241,CHIM COORDINAT LAB,205 ROUTE NARBONNE,F-31077 TOULOUSE,FRANCE

[2] INST NATL POLYTECH TOULOUSE,CNRS,UPR 8241,CHIM COORDINAT LAB,F-31077 TOULOUSE,FRANCE

来源：

ORGANOMETALLICS | 1993年 / 12卷 / 01期

关键词：

D O I：

10.1021/om00025a006

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The versatile reactivity of the electrophilic fragment Cp*Ru+ toward unsaturated acyclic hydrocarbons is described: stoichiometric cyclization with 1,3,5-hexatriene and metathesis with 1,7-octadiene as well as catalytic isomerization and/or oligomerization with 1,4-pentadiene, 1,5-hexadiene, 1-hexene, and neohexene. In the case of neohexene, a novel reaction catalytically producing CH4 and C-11 and C-17 hydrocarbons is reported.

引用

页码：13 / 14

页数：2

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