THE PHOTOLYTIC DISPROPORTIONATION OF DIALKYL 2,2-DI(PHENYLSELENO)PROPANEDIOATES

被引：1

作者：

BYERS, JH

THISSELL, JG

机构：

[1] Department of Chemistry and Biochemistry, Middlebury College, Middlebury

来源：

SYNTHETIC COMMUNICATIONS | 1995年 / 25卷 / 01期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1080/00397919508010784

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Dialkyl-2,2-di(phenylseleno)propanedioates undergo disproportionation to form tetralkyl 1,1,2,2-ethylene tetracarboxylates and diphenyl diselenide upon photolysis. Evidence for the intermediacy of a capto-dative radical intermediate in this process is described.

引用

页码：21 / 26

页数：6

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