PHOTOCONDENSATION IN POLYCRYSTALLINE MIXTURES OF ARYLACETIC ACIDS AND 1,2,4,5-TETRACYANOBENZENE

被引：13

作者：

KOSHIMA, H

DING, KL

MIYAHARA, I

HIROTSU, K

KANZAKI, M

MATSUURA, T

机构：

[1] RYUKOKU UNIV,FAC SCI & TECHNOL,DEPT CHEM MAT,OTSU,SHIGA 52021,JAPAN

[2] OSAKA CITY UNIV,FAC SCI,DEPT CHEM,SUMIYOSHI KU,OSAKA 558,JAPAN

来源：

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY | 1995年 / 87卷 / 03期

关键词：

PHOTOCONDENSATION; POLYCRYSTALLINE MIXTURES; ARYLACETIC ACIDS; 1,2,4,5-TETRACYANOBENZENE;

D O I：

10.1016/1010-6030(94)03996-8

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Irradiation of simple polycrystalline mixtures (1:1 molar ratios) of phenylacetic acids, such as 4-tolylacetic acid and 4-methoxyphenylacetic acid, and 1,2,4,5-tetracyanobenzene caused decarboxylations followed by dehydrocyanating condensation to give monobenzyltricyanobenzenes and dibenzyldicyanobenzenes. In the case of a polycrystalline mixture of 9-fluorenecarboxylic acid and tetracyanobenzene, the decarboxylation product 9-fluorene was obtained as the main product. The reactions proceed at the interface of the component crystallites. The product selectivities were different from those of the solution reactions.

引用

页码：219 / 223

页数：5

共 50 条

[1] Photocondensation in polycrystalline mixtures of arylacetic acids and 1,2,4,5-tetracyanobenzene
Koshima, H.
Ding, K.
Miyahara, I.
Hirotsu, K.
[J]. Journal of Photochemistry and Photobiology, A: Chemistry, 87 (03):
[2] Spectroscopic characterization of 1,2,4,5-tetracyanobenzene
Chakraborty, S.
Wategaonkar, S.
[J]. CHEMICAL PHYSICS LETTERS, 2008, 460 (1-3) : 18 - 22
[3] PHOTOREACTION OF 1,2,4,5-TETRACYANOBENZENE WITH TETRAHYDROFURAN
OHASHI, M
TSUJIMOTO, K
[J]. CHEMISTRY LETTERS, 1975, (08) : 829 - 830
[4] Solid-state photodecarboxylation induced by exciting the CT bands of the complexes of arylacetic acids and 1,2,4,5-tetracyanobenzene
Koshima, H
Ding, KL
Chisaka, Y
Matsuura, T
Ohashi, Y
Mukasa, M
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1996, 61 (07): : 2352 - 2357
[5] PHOTOSUBSTITUTION OF 1,2,4,5-TETRACYANOBENZENE BY ETHERS
OHASHI, M
TSUJIMOTO, K
FURUKAWA, Y
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1979, (05): : 1147 - 1149
[6] PHOTO-SUBSTITUTION OF 1,2,4,5-TETRACYANOBENZENE BY TOLUENE
YOSHINO, A
YAMASAKI, K
YONEZAWA, T
OHASHI, M
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1975, (08): : 735 - 737
[7] CRYSTAL STRUCTURE OF 1 - 1 COMPLEX OF NAPHTHALENE WITH 1,2,4,5-TETRACYANOBENZENE
KUMAKURA, S
IWASAKI, F
SAITO, Y
[J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1967, 40 (08) : 1826 - +
[8] Radiative exciplexes of 1,2,4,5-tetracyanobenzene with sterically hindered alkylbenzenes
Zhou, JW
Zhong, C
Francis, TM
Braun, CL
[J]. JOURNAL OF PHYSICAL CHEMISTRY A, 2003, 107 (40): : 8319 - 8326
[9] CRYSTAL STRUCTURE OF 1 - 1 COMPLEX OF 1,2,4,5-TETRACYANOBENZENE AND HEXAMETHYLBENZENE
NIIMURA, N
OHASHI, Y
SAITO, Y
[J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1968, 41 (08) : 1815 - +
[10] OCTA-SUBSTITUTED PHTHALOCYANINES FROM 1,2,4,5-TETRACYANOBENZENE
WOHRLE, D
WAHL, B
[J]. TETRAHEDRON LETTERS, 1979, (03) : 227 - 228

← 1 2 3 4 5 →