ESR detection of N2O+ in gamma-irradiated N2O at 77 degrees K

被引：5
|
作者：
Smith, D. H. [1 ]
Seddon, W. A. [1 ]
机构：
[1] Atom Energy Canada Ltd, Chalk River Nucl Labs, Res Chem Branch, Chalk River, ON K0J 1J0, Canada
来源：
CHEMICAL PHYSICS LETTERS | 1969年 / 3卷 / 08期
关键词：
D O I：
10.1016/0009-2614(69)85130-4
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Gamma irradiation of solid N2O at 77 degrees K results in the formation of at least three different radical species. This note describes the detection of a new radical species containing two non-equivalent nitrogen atoms. Our data indicate this species is N2O+ since the major hyperfine splitting arises from the terminal nitrogen.
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页码：640 / 642
页数：3
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