ELECTROORGANIC CHEMISTRY .130. A NOVEL TRIFLUOROMETHYLATION OF ALDEHYDES AND KETONES PROMOTED BY AN ELECTROGENERATED BASE

被引：114
|
作者：
SHONO, T
ISHIFUNE, M
OKADA, T
KASHIMURA, S
机构：
[1] Department of Synthetic Chemistry, Faculty of Engineering, Kyoto University, Yoshida, Sakyo
来源：
JOURNAL OF ORGANIC CHEMISTRY | 1991年 / 56卷 / 01期
关键词：
D O I：
10.1021/jo00001a002
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A base generated by the electroreduction of 2-pyrrolidone deprotonated trifluoromethane to form a trifluoromethyl anion equivalent. In the presence of hexamethyldisilazane, this species reacted with a variety of aldehydes and ketones to afford (trifluoromethyl)-carbinols in high yield.
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页码：2 / 4
页数：3
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