INVESTIGATION OF THE MICROSTRUCTURE OF POLY(DIALLYLDIMETHYLAMMONIUM CHLORIDE) BY NITROGEN-14(15) NMR-SPECTROSCOPY

被引：17
|
作者：
MASTERMAN, TC [1 ]
DANDO, NR [1 ]
WEAVER, DG [1 ]
SEYFERTH, D [1 ]
机构：
[1] ALCOA LABS,ALCOA CTR,PA 15069
来源：
JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS | 1994年 / 32卷 / 13期
关键词：
PDAMC; CYCLOPOLYMERIZATION; CYCLOPOLYMER; POLY (DIALLYLDIMETHYLAMMONIUM CHLORIDE); CPMAS; N-14; N-15;
D O I：
10.1002/polb.1994.090321313
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
CPMAS C-13 and N-15 solid-state NMR spectroscopy, as well as solution state N-14 NMR spectroscopy, was used to investigate the microstructure of poly(diallyldimethylammonium chloride). The results of these studies, supported by N-14 NMR studies of model compounds, were in agreement with the earlier conclusion of other workers (via solution state C-13 NMR spectroscopy) that the polymer consists of a chain of five-membered pyrrolidinium rings, A. [GRAPHICS] (C) 1994 John Wiley and Sons, Inc.
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页码：2263 / 2270
页数：8
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