THEORY OF ELECTROPHORETIC MOBILITY OF POLYELECTROLYTE CHAINS

被引：18
|
作者：
MUTHUKUMAR, M [1 ]
机构：
[1] UNIV MASSACHUSETTS,MAT RES LAB,AMHERST,MA 01003
来源：
MACROMOLECULAR THEORY AND SIMULATIONS | 1994年 / 3卷 / 01期
关键词：
D O I：
10.1002/mats.1994.040030105
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
An explicit formula is derived for the electrophoretic mobility of a linear polyelectrolyte chain in terms of the molecular weight, Debye length and solvent quality. The nature of the crossover between different regimes as the salt concentration and molecular weight are varied is presented. The effect of chain statistics intermediate between the Gaussian and rodlike limits on the electrophoretic mobility is analysed for the first time.
引用
下载
收藏
页码：61 / 71
页数：11
相关论文
共 50 条
  • [1] Theory of electrophoretic mobility of a polyelectrolyte in semidilute solutions of neutral polymers
    Muthukumar, M
    ELECTROPHORESIS, 1996, 17 (06) : 1167 - 1172
  • [2] ELECTROPHORETIC MOBILITY OF WORMLIKE CHAINS .2. THEORY
    CLELAND, RL
    MACROMOLECULES, 1991, 24 (15) : 4391 - 4402
  • [3] ELECTROPHORETIC MOBILITY IN POLYELECTROLYTE SOLUTIONS
    BERNARD, O
    TURQ, P
    BLUM, L
    JOURNAL OF PHYSICAL CHEMISTRY, 1991, 95 (23): : 9508 - 9513
  • [4] Electrophoretic Mobility of a Polyelectrolyte Capsule
    Roldughin, V. I.
    Filippov, A. N.
    Kharitonova, T. V.
    COLLOID JOURNAL, 2018, 80 (02) : 189 - 198
  • [5] Electrophoretic Mobility of a Polyelectrolyte Capsule
    V. I. Roldughin
    A. N. Filippov
    T. V. Kharitonova
    Colloid Journal, 2018, 80 : 189 - 198
  • [6] The Relationship between Electrophoretic Mobility and Polyelectrolyte Charge
    Stellwagen, Nancy C.
    BIOPHYSICAL JOURNAL, 2015, 108 (02) : 396A - 396A
  • [7] Lateral mobility of polyelectrolyte chains in multilayers
    Nazaran, P.
    Bosio, V.
    Jaeger, W.
    Anghel, D. F.
    v. Klitzing, R.
    JOURNAL OF PHYSICAL CHEMISTRY B, 2007, 111 (29): : 8572 - 8581
  • [8] REDUCED ELECTROPHORETIC MOBILITY OF COLLAGEN CHAINS UPON CARBAMYLATION
    ROYCE, PM
    GITZELMANN, R
    STEINMANN, B
    BIOLOGICAL CHEMISTRY HOPPE-SEYLER, 1985, 366 (09): : 841 - 841
  • [9] THEORY OF ELECTROPHORETIC MOBILITY IN STABILIZED MEDIA
    BOYACK, JR
    GIDDINGS, JC
    ARCHIVES OF BIOCHEMISTRY AND BIOPHYSICS, 1963, 100 (01) : 16 - &
  • [10] Interplay between electrophoretic mobility and intrinsic viscosity of polypeptide chains
    Deiber, Julio A.
    Peirotti, Marta B.
    Piaggio, Maria V.
    ELECTROPHORESIS, 2012, 33 (06) : 990 - 999
12345