A thin boron film has been applied to the DIII-D tokamak plasma facing surfaces to reduce impurity influx, particularly oxygen and carbon. A direct result of this surface modification was the observation of a regime of very high energy confinement, VH-mode, with confinement times from 1.5 to 2 times greater than predicted by the H-mode scaling relation for the same set of parameters. VH-mode discharges are characterized by low ohmic target densities, low edge neutral pressure, and reduced recycling. These conditions have reduced the collisionality nu* in the edge region producing a higher edge pressure gradient and a significant bootstrap current, up to 30% of the total current. We will describe the edge plasma properties after boronization including reductions in recycling inferred from measurements of tau(p)*. In particular we will discuss the edge plasma conditions necessary for access to VH-mode including the boronization process and properties of the deposited film.